Transformation of 2,4-dichlorophenol by H2O2/UV-C, Fenton and photo-Fenton processes: Oxidation products and toxicity evolution

被引：95
作者：
Karci, Akin [2 ]
Arslan-Alaton, Idil [1 ]
Olmez-Hanci, Tugba [1 ]
Bekbolet, Miray [2 ]
机构：
[1] Istanbul Tech Univ, Fac Civil Engn, Dept Environm Engn, TR-34469 Istanbul, Turkey
[2] Bogazici Univ, Inst Environm Sci, TR-34342 Istanbul, Turkey
来源：
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2012年 / 230卷 / 01期
关键词：
2,4-Dichlorophenol (2,4 DCP); Acutetoxicity; Fenton; Photo-Fenton; H2O2/UV-C; Oxidation product; HYDROGEN-PEROXIDE; ELECTROCHEMICAL OXIDATION; ULTRAVIOLET-RADIATION; PROCESS OPTIMIZATION; AQUEOUS-SOLUTIONS; P-CHLOROPHENOL; ELECTRO-FENTON; DAPHNIA-MAGNA; DEGRADATION; PHENOL;
D O I：
10.1016/j.jphotochem.2012.01.003
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the present study, H2O2/UV-C, Fenton and photo-Fenton treatment of 2,4-dichlorophenol was compared in terms of oxidation products and acute toxicity. The oxidation products were identified by gas chromatography-mass spectroscopy, high performance liquid chromatography and ion chromatography, whereas changes in acute toxicity were evaluated by the Vibrio fischeri luminescence inhibition assay. H2O2/UV-C and photo-Fenton processes ensured complete 2,4-dichlorophenolremoval, detoxification and significant mineralization. Hydroquinone and formic acid were identified as the common oxidation products of the studied advanced oxidation processes investigated. 3,5-dichloro-2-hydroxybenzaldehyde, phenol, 4-chlorophenol and 2,5-dichlorohydroquinone were identified as the additional H2O2/UV-C oxidation products of 2,4-dichlorophenol. Acute toxicity decreased with decreasing 2,4-dichlorophenol and increasing chloride release. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：65 / 73
页数：9
相关论文
共 50 条
[41]   Photochemical treatment of 2-chlorophenol aqueous solutions using ultraviolet radiation, hydrogen peroxide and photo-Fenton reaction [J].
Poulopoulos, S. G. ;
Nikolaki, M. ;
Karampetsos, D. ;
Philippopoulos, C. J. .
JOURNAL OF HAZARDOUS MATERIALS, 2008, 153 (1-2) :582-587
[42]   Bioassays as a tool for evaluating advanced oxidation processes in water and wastewater treatment [J].
Rizzo, Luigi .
WATER RESEARCH, 2011, 45 (15) :4311-4340
[43]   Oxidation by-products and ecotoxicity assessment during the photodegradation of fenofibric acid in aqueous solution with UV and UV/H2O2 [J].
Santiago, Javier ;
Agueera, Ana ;
del Mar Gomez-Ramos, Maria ;
Fernandez Alba, Amadeo R. ;
Garcia-Calvo, Eloy ;
Rosal, Roberto .
JOURNAL OF HAZARDOUS MATERIALS, 2011, 194 :30-41
[44]   Evolution of toxicity upon wet catalytic oxidation of phenol [J].
Santos, A ;
Yustos, P ;
Quintanilla, A ;
García-Ochoa, F ;
Casas, JA ;
Rodríguez, JJ .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (01) :133-138
[45]   Applicability of Fenton and H2O2/UV reactions in the treatment of tannery wastewaters [J].
Schrank, SG ;
José, HJ ;
Moreira, RFPM ;
Schröder, HF .
CHEMOSPHERE, 2005, 60 (05) :644-655
[46]   Degradation of sulfamethoxazole in water by solar photo-Fenton. Chemical and toxicological evaluation [J].
Trovo, Alam G. ;
Nogueira, Raquel F. P. ;
Aguera, Ana ;
Fernandez-Alba, Amadeo R. ;
Sirtori, Carla ;
Malato, Sixto .
WATER RESEARCH, 2009, 43 (16) :3922-3931
[47]   Uptake, removal, accumulation, and phytotoxicity of 4-chlorophenol in willow trees [J].
Ucisik, A. S. ;
Trapp, S. .
ARCHIVES OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY, 2008, 54 (04) :619-627
[48]   Effects of experimental parameters on 2,4-dichlorphenol degradation over Er-chitosan-PbO2 electrode [J].
Wang, Ying ;
Shen, Zhenyao ;
Chen, Xiaochun .
JOURNAL OF HAZARDOUS MATERIALS, 2010, 178 (1-3) :867-874
[49]   Evolution of ecotoxicity upon Fenton's oxidation of phenol in water [J].
Zazo, J. A. ;
Casas, J. A. ;
Molina, C. B. ;
Quintanilla, A. ;
Rodriguez, J. J. .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2007, 41 (20) :7164-7170
[50]   Fenton's oxidation of pentachlorophenol [J].
Zimbron, Julio A. ;
Reardon, Kenneth F. .
WATER RESEARCH, 2009, 43 (07) :1831-1840
12345