Trifluoromethylfluorosulfonylation of Unactivated Alkenes Using Readily Available Ag(O2CCF2SO2F) and N-Fluorobenzenesulfonimide

被引：79

作者：

Liu, Yongan ^{[1
]}

Wu, Hao ^{[1
]}

Guo, Yong ^{[1
]}

Xiao, Ji-Chang ^{[1
]}

Chen, Qing-Yun ^{[1
]}

Liu, Chao ^{[1
]}

机构：

[1] Chinese Acad Sci, Key Lab Organofluorine Chem, Shanghai Inst Organ Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 48期

基金：

中国国家自然科学基金;

关键词：

alkenes; fluorine; radicals; reaction mechanisms; synthetic methods; ADDITION-REACTIONS; TRIFLUOROMETHYLATION; MIGRATION; COPPER; FLUOROALKYLATION; FLUORINE; REAGENT; CATALYSIS; STRATEGY; OLEFIN;

D O I：

10.1002/anie.201709663

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Presented is a novel intermolecular radical trifluoromethylfluorosulfonylation of unactivated alkenes under mild reaction conditions with good functional-group tolerance in the most atom-economic manner by using readily available Ag(O2CCF2SO2F) and N-fluorobenzenesulfonimide (NFSI). Both the trifluoromethyl and sulfonyl groups in the products originate from Ag(O2CCF2SO2F).

引用

页码：15432 / 15435

页数：4

共 62 条

[41] Shining Light on Copper: Unique Opportunities for Visible-Light-Catalyzed Atom Transfer Radical Addition Reactions and Related Processes [J].