Copper Nanoparticles Installed in Metal-Organic Framework Thin Films are Electrocatalytically Competent for CO2 Reduction

被引：163

作者：

Kung, Chung-Wei ^{[1
]}

Audu, Cornelius O. ^{[1
]}

Peters, Aaron W. ^{[1
]}

Noh, Hyunho ^{[1
]}

Farha, Omar K. ^{[1
,2
]}

Hupp, Joseph T. ^{[1
,3
]}

机构：

[1] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA

[2] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah, Saudi Arabia

[3] Argonne Natl Lab, 9700 South Cass Ave, Argonne, IL 60439 USA

来源：

ACS ENERGY LETTERS | 2017年 / 2卷 / 10期

关键词：

ATOMIC LAYER DEPOSITION; CARBON-DIOXIDE; ELECTROCHEMICAL REDUCTION; WATER OXIDATION; CU NANOPARTICLES; CLIMATE-CHANGE; SINGLE-SITE; ELECTRODES; CATALYSTS; SURFACES;

D O I：

10.1021/acsenergylett.7b00621

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Copper nanoparticles are embedded into a solvothermally grown thin film of a zirconium metal-organic framework (MOF), NU-1000, by installing single-site Cu(II) into the NU-1000 thin film via solvothermal deposition in MOFs (SIM) followed by electrochemical reduction of Cu(II) to metallic Cu. The obtained Cu nanoparticles are electrochemically addressable and exhibit promising electrocatalytic activity for CO2 reduction in an aqueous electrolyte.

引用

页码：2394 / 2401

页数：8

共 73 条

[21] The Chemistry and Applications of Metal-Organic Frameworks [J].

Furukawa, Hiroyasu ;

Cordova, Kyle E. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2013, 341 (6149) :974-+

[22] Stability limits of tin-based electrocatalyst supports [J].

Geiger, Simon ;

Kasian, Olga ;

Mingers, Andrea M. ;

Mayrhofer, Karl J. J. ;

Cherevko, Serhiy .

SCIENTIFIC REPORTS, 2017, 7

[23] Highly efficient electro-reduction of CO2 to formic acid by nano-copper [J].

Gupta, Kalyani ;

Bersani, Marco ;

Darr, Jawwad A. .

JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (36) :13786-13794

[24] Volcanic carbon dioxide vents show ecosystem effects of ocean acidification [J].

Hall-Spencer, Jason M. ;

Rodolfo-Metalpa, Riccardo ;

Martin, Sophie ;

Ransome, Emma ;

Fine, Maoz ;

Turner, Suzanne M. ;

Rowley, Sonia J. ;

Tedesco, Dario ;

Buia, Maria-Cristina .

NATURE, 2008, 454 (7200) :96-99

[25] ELECTROCATALYSIS Powered by porphyrin packing [J].

Hod, Idan ;

Farha, Omar K. ;

Hupp, Joseph T. .

NATURE MATERIALS, 2015, 14 (12) :1192-1193

[26] Fe-Porphyrin-Based Metal-Organic Framework Films as High-Surface Concentration, Heterogeneous Catalysts for Electrochemical Reduction of CO2 [J].

Hod, Idan ;

Sampson, Matthew D. ;

Deria, Pravas ;

Kubiak, Clifford P. ;

Farha, Omar K. ;

Hupp, Joseph T. .

ACS CATALYSIS, 2015, 5 (11) :6302-6309

[27] A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution [J].

Hod, Idan ;

Deria, Pravas ;

Bury, Wojciech ;

Mondloch, Joseph E. ;

Kung, Chung-Wei ;

So, Monica ;

Sampson, Matthew D. ;

Peters, Aaron W. ;

Kubiak, Cliff P. ;

Farha, Omar K. ;

Hupp, Joseph T. .

NATURE COMMUNICATIONS, 2015, 6

[28] Depletion of fossil fuels and anthropogenic climate change-A review [J].

Hook, Mikael ;

Tang, Xu .

ENERGY POLICY, 2013, 52 :797-809

[29] FORMATION OF HYDROCARBONS IN THE ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE AT A COPPER ELECTRODE IN AQUEOUS-SOLUTION [J].

HORI, Y ;

MURATA, A ;

TAKAHASHI, R .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1989, 85 :2309-2326

[30] Electrochemical reduction of CO at a copper electrode [J].

Hori, Y ;

Takahashi, R ;

Yoshinami, Y ;

Murata, A .

JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (36) :7075-7081

← 1 2 3 4 5 6 7 8 →