Copper Nanoparticles Installed in Metal-Organic Framework Thin Films are Electrocatalytically Competent for CO2 Reduction

被引：163

作者：

Kung, Chung-Wei ^{[1
]}

Audu, Cornelius O. ^{[1
]}

Peters, Aaron W. ^{[1
]}

Noh, Hyunho ^{[1
]}

Farha, Omar K. ^{[1
,2
]}

Hupp, Joseph T. ^{[1
,3
]}

机构：

[1] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA

[2] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah, Saudi Arabia

[3] Argonne Natl Lab, 9700 South Cass Ave, Argonne, IL 60439 USA

来源：

ACS ENERGY LETTERS | 2017年 / 2卷 / 10期

关键词：

ATOMIC LAYER DEPOSITION; CARBON-DIOXIDE; ELECTROCHEMICAL REDUCTION; WATER OXIDATION; CU NANOPARTICLES; CLIMATE-CHANGE; SINGLE-SITE; ELECTRODES; CATALYSTS; SURFACES;

D O I：

10.1021/acsenergylett.7b00621

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Copper nanoparticles are embedded into a solvothermally grown thin film of a zirconium metal-organic framework (MOF), NU-1000, by installing single-site Cu(II) into the NU-1000 thin film via solvothermal deposition in MOFs (SIM) followed by electrochemical reduction of Cu(II) to metallic Cu. The obtained Cu nanoparticles are electrochemically addressable and exhibit promising electrocatalytic activity for CO2 reduction in an aqueous electrolyte.

引用

页码：2394 / 2401

页数：8

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