Effect of heat treatment on the electrical properties of Li2O-P2O5 glasses

被引:0
作者
Li Tongwei [1 ]
Wan Yun
Peng Wu
Gong Jianghong
机构
[1] NW Univ Xian, Dept Phys, Xian 710069, Peoples R China
[2] Tsing Hua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China
关键词
lithium phosphate glasses; conductivity; activation energy; heat treatment; transition temperature;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Lithium phosphate glass powder was prepared by quenching the melt in water. Then the glass samples were prepared by dry-pressing and heat-treatment and their electrical properties were examined. It was found that the variation of the activation energy for conduction, E, for samples heat-treated at temperature lower than the transition temperature (T-g) is different from that for samples heat-treated at temperature higher than T-g. As the heat-treatment time prolongs, however, E for all the examined samples gradually tends to a constant. A possible explanation for this experimental phenomenon was proposed based on analyzing the effect of heat-treatment on the microstructure of the samples.
引用
收藏
页码:328 / 330
页数:3
相关论文
共 5 条
[1]   Local structure and connectivity in lithium phosphate glasses:: a solid-state 31P MAS NMR and 2D exchange investigation [J].
Alam, TM ;
Brow, RK .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 223 (1-2) :1-20
[2]   6Li, 7Li nuclear magnetic resonance investigation of lithium coordination in binary phosphate glasses [J].
Alam, TM ;
Conzone, S ;
Brow, RK ;
Boyle, TJ .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1999, 258 (1-3) :140-154
[3]   DC AND AC CONDUCTIVITY IN WIDE COMPOSITION RANGE LI2O-P2O5 GLASSES [J].
MARTIN, SW ;
ANGELL, CA .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1986, 83 (1-2) :185-207
[4]   Glasses and supercooled melts in the Li2O-P2O5 system [J].
Pakhomov, GB ;
Neverov, SL .
SOLID STATE IONICS, 1999, 119 (1-4) :235-244
[5]   Structural study of lithium phosphate glasses by X-ray RDF and computer simulations [J].
Sistla, RK ;
Seshasayee, M .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2004, 349 :22-29