Synthesis and characterisation of high-nuclearity osmium-silver mixed-metal clusters

被引：7
|
作者：
Lee, Yui-Bing [1 ]
Wong, Wing-Tak [1 ]
机构：
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2007年 / 38期
关键词：
D O I：
10.1039/b709860j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of the triosmium cluster anion, [Os-3(mu-H)(CO)(11)]-[PPN] (PPN = [N(PPh3)(2)](+)), with [AgPF6] in the presence of [Ir(PPh3)(2)(CO)Cl] in THF at room temperature affords two new high-nuclearity osmium - silver clusters, [Os13Ag9(CO)(48)]-[PPN] (1) and [Os9Ag9(mu(3)-O)(2)(CO)(30)][PPN] (2), and an iridium complex, [Ir(PPh3)(2)(CO)Cl(O-2)] (3).
引用
收藏
页码：3924 / 3926
页数：3
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