Facile simultaneous defect production and O,N-doping of carbon nanotubes with unexpected catalytic performance for clean and energy-saving production of styrene

被引:29
作者
Zhao, Zhongkui [1 ]
Dai, Yitao [1 ]
Ge, Guifang [1 ]
Guo, Xinwen [1 ]
Wang, Guiru [1 ]
机构
[1] Dalian Univ Technol, Sch Chem Engn, Dept Catalysis Chem & Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China
基金
中国国家自然科学基金;
关键词
NITROGEN-DOPED GRAPHENE; OXIDATIVE DEHYDROGENATION; ETHYLBENZENE; OXIDE; HYDROTALCITE; NANOCOMPOSITE; NANOCARBON; PRECURSORS; REACTIVITY; PROPANE;
D O I
10.1039/c5gc00971e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
O,N-doped carbon nanotubes with increased structural defects and enriched surface ketonic C=O groups (MN-CNT), prepared by a facile and low-cost one-step strategy, demonstrate unexpected catalytic performance in direct dehydrogenation of ethylbenzene for styrene production with clean and energy-saving features. This work paves a new avenue for preparing other highly-efficient carbocatalysts in diverse organic transformations.
引用
收藏
页码:3723 / 3727
页数:5
相关论文
共 45 条
[1]   AN INFRARED STUDY OF THE DEHYDROGENATION OF ETHYLBENZENE TO STYRENE OVER IRON-BASED CATALYSTS [J].
ADDIEGO, WP ;
ESTRADA, CA ;
GOODMAN, DW ;
ROSYNEK, MP .
JOURNAL OF CATALYSIS, 1994, 146 (02) :407-414
[2]   Structural changes and surface activities of ethylbenzene dehydrogenation catalysts during deactivation [J].
Baghalha, Morteza ;
Ebrahimpour, Omid .
APPLIED CATALYSIS A-GENERAL, 2007, 326 (02) :143-151
[3]   Ethylbenzene dehydrogenation over binary FeOx-MeOy/Mg(Al)O catalysts derived from hydrotalcites [J].
Balasamy, Rabindran J. ;
Khurshid, Alam ;
Al-Ali, Ali A. S. ;
Atanda, Luqman A. ;
Sagata, Kunimasa ;
Asamoto, Makiko ;
Yahiro, Hidenori ;
Nomura, Kiyoshi ;
Sano, Tsuneji ;
Takehira, Katsuomi ;
Al-Khattaf, Sulaiman S. .
APPLIED CATALYSIS A-GENERAL, 2010, 390 (1-2) :225-234
[4]   HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].
Cavani, F. ;
Trifiro, F. ;
Vaccari, A. .
CATALYSIS TODAY, 1991, 11 (02) :173-301
[5]   Alternative processes for the production of styrene [J].
Cavani, F ;
Trifiro, F .
APPLIED CATALYSIS A-GENERAL, 1995, 133 (02) :219-239
[6]   Amorphous carbon enriched with pyridinic nitrogen as an efficient metal-free electrocatalyst for oxygen reduction reaction [J].
Chen, Jingyan ;
Wang, Xin ;
Cui, Xiaoqiang ;
Yang, Guangmin ;
Zheng, Weitao .
CHEMICAL COMMUNICATIONS, 2014, 50 (05) :557-559
[7]   Identifying Active Functionalities on Few-Layered Graphene Catalysts for Oxidative Dehydrogenation of Isobutane [J].
Dathar, Gopi Krishna Phani ;
Tsai, Yu-Tung ;
Gierszal, Kamil ;
Xu, Ye ;
Liang, Chengdu ;
Rondinone, Adam J. ;
Overbury, Steven H. ;
Schwartz, Viviane .
CHEMSUSCHEM, 2014, 7 (02) :483-491
[8]   Reduced graphene oxide as a catalyst for hydrogenation of nitrobenzene at room temperature [J].
Gao, Yongjun ;
Ma, Ding ;
Wang, Chunlei ;
Guan, Jing ;
Bao, Xinhe .
CHEMICAL COMMUNICATIONS, 2011, 47 (08) :2432-2434
[9]   INSITU CATALYST REACTIVATION - USED ETHYLBENZENE DEHYDROGENATION CATALYST WITH AGGLOMERATED POTASSIUM PROMOTER [J].
HERZOG, BD ;
RASE, HF .
INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1984, 23 (02) :187-196
[10]   Open-Cage Fullerene-like Graphitic Carbons as Catalysts for Oxidative Dehydrogenation of Isobutane [J].
Liang, Chengdu ;
Xie, Hong ;
Schwartz, Viviane ;
Howe, Jane ;
Dai, Sheng ;
Overbury, Steven H. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (22) :7735-7741