Anionic σ-complexes of 1,3,5-tris(fluorosulfonyl)benzene

被引：8
|
作者：
Boiko, Vladimir N. [1 ]
Kamoshenkova, Oksana M. [1 ]
Filatov, Andrey A. [1 ]
机构：
[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02660 Kiev 94, Ukraine
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 17期
关键词：
1,3,5-Tris(fluorosulfonyl)benzene; anionic sigma-complexes; aromatic sulfonic-acid fluorides; aromatic nucleophilic addition;
D O I：
10.1016/j.tetlet.2008.02.151
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We have found that symmetrical benzene trisulfonic-acid trifluoride 1 is able to undergo nucleophilic addition at free positions on the aromatic ring. Its reactions with sodium sulfite, morpholine and carbanions of malonic and acetoacetic esters, dimedone and nitromethane lead to the formation of comparatively stable anionic sigma-complexes 3-8. (c) 2008 Published by Elsevier Ltd.
引用
收藏
页码：2719 / 2721
页数：3
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