SERS detection of polychlorinated biphenyls using β-cyclodextrin functionalized gold nanoparticles on agriculture land soil

被引:36
作者
Jency, D. Arockia [1 ]
Umadevi, M. [1 ]
Sathe, G. V. [2 ]
机构
[1] Mother Teresa Womens Univ, Dept Phys, Kodaikanal 624101, India
[2] UGC DAE Consortium Sci Res, Indore 452017, Madhya Pradesh, India
关键词
gold nanoparticles; -CD; persistent organic pollutant; TEM; SERS; ENHANCED RAMAN-SCATTERING; PERSISTENT ORGANIC POLLUTANTS; RAPID DETECTION; SPECTROSCOPY; DNA; ENVIRONMENT; CHEMISTRY; PROBE; PCBS;
D O I
10.1002/jrs.4654
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
A highly sensitive surface-enhanced Raman scattering (SERS) platform for the selective trace analysis of persistent organic pollutant (POP) such as polychlorinated biphenyl (PCBs) was reported based on -CD modified gold nanoparticles (AuNPs) with the real environmental sample of polluted soil. The synthesized gold nanoparticles were characterized using UV-vis spectroscopy, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and transmission electron microscopy (TEM). In polluted soil the presentation of PCB is confirmed by using GC-MS. It is further verified and confirmed by using SERS. When the contaminated soil was added to the system, the binding of soil with -CD resulted in the aggregation of AuNPs, and excellent Raman signal was obtained which can reflect the isomers of polychlorinated biphenyls. Copyright (c) 2015 John Wiley & Sons, Ltd.
引用
收藏
页码:377 / 383
页数:7
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