A quasi-solid-state dye-sensitized solar cell based on porous polymer electrolyte membrane

被引：15
作者：
Zhang, Xiao [1 ,2 ]
Wang, Cong-Xiao [1 ,2 ]
Li, Fu-You [3 ]
Xia, Yong-Yao [1 ,2 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[3] Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China
来源：
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2008年 / 194卷 / 01期
关键词：
quasi-solid-state dye-sensitized solar cell; gel polymer electrolyte; porous membrane;
D O I：
10.1016/j.jphotochem.2007.07.011
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Water was employed as plasticizer to produce porous polymer membrane. The gel polymer electrolyte containing 72% liquid organic electrolyte (0.5 M LiI, 0.05 M I-2, 0.5 M 4-tert-butylpyridine in PC) shows ionic conductivity of 6.4 x 10(-4) S cm(-1) due to its high porous structure. Moreover, the porous electrolyte membrane shows good mechanical strength and serves as a separator in the solar cells. Quasi-solid-state solar cells fabricated with this gel electrolyte displayed energy conversion efficiency of 6.0% when the cell gap was tuned to 30 pm. Moreover, these cells possessed much better long-term stability compared with those based on liquid organic electrolyte. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：31 / 36
页数：6
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