Aziridines versus vinyl carbamates from the direct amination of electron-withdrawing group-substituted trifluoromethyl enoates

被引：35

作者：

Fioravanti, S ^{[1
]}

Colantoni, D ^{[1
]}

Pellacani, L ^{[1
]}

Tardella, PA ^{[1
]}

机构：

[1] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 08期

关键词：

D O I：

10.1021/jo050044w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aza-MIRC (Michael-initiated ring closure) and C-H insertion products were obtained in the reactions of trifluoro-methylated olefins with different nosyloxycarbamates by changing base and solvent. Aza-Michael addition products were not isolated. The presence and the position of the trifluoromethyl group allow control of the outcome of the reactions.

引用

页码：3296 / 3298

页数：3

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