Cp☆ Iridium Complexes Give Catalytic Alkane Hydroxylation with Retention of Stereochemistry

被引：96

作者：

Zhou, Meng ^{[1
]}

Schley, Nathan D. ^{[1
]}

Crabtree, Robert H. ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 36期

关键词：

WATER OXIDATION; H ACTIVATION; BOND; HYDROCARBONS;

D O I：

10.1021/ja1058247

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of (CpIr)-Ir-star complexes can catalyze C-H oxidation, with ceric ammonium nitrate as the terminal oxidant and water as the source of oxygen. Remarkably the hydroxylation of cis-decalin and 1,4-dimethylcyclohexane proceeds with retention of stereochemistry. With H2O18, cis-decalin oxidation gave O-18 incorporation into the product cis-decalol.

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页码：12550 / 12551

页数：2

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