A diastereoselective total synthesis of the sesquiterpene (±)-mutisianthol

被引：29

作者：

Ferraz, HMC ^{[1
]}

Aguilar, AM ^{[1
]}

Silva, LF ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, Dept Quim, BR-05513970 Sao Paulo, Brazil

来源：

TETRAHEDRON | 2003年 / 59卷 / 31期

基金：

巴西圣保罗研究基金会;

关键词：

indan; total synthesis; ring contraction; thallium(III);

D O I：

10.1016/S0040-4020(03)00974-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The total synthesis of the phenolic sesquiterpene mutisianthol has been accomplished in 12 steps from the readily available 2-methylanisole. The required trans-1,3-disubstituted indan intermediate was obtained through a diastereoselective thallium(111) mediated ring contraction of a 1-methyl-1,2-dihydronaphthalene derivative. (C) 2003 Published by Elsevier Ltd.

引用

页码：5817 / 5821

页数：5

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