A facile synthesis of highly ordered mesoporous carbon monolith with mechanically stable mesostructure and superior conductivity from SBA-15 powder

被引:48
作者
Wang, LF
Lin, S
Lin, KF
Yin, CY
Liang, DS
Di, Y
Fan, PW
Jiang, DZ
Xiao, FS [1 ]
机构
[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
[2] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China
基金
中国国家自然科学基金;
关键词
mesoporous carbon monolith; SBA-15; powder; tailorable size and shape; mechanically stable mesostructure; conductivity;
D O I
10.1016/j.micromeso.2005.06.005
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A highly ordered mesoporous carbon monolith has been successfully synthesized from the template of SBA-15 powder. Interestingly, not only the size and shape of the mesoporous carbon monolith could be simply tailored by controlling the size and shape of a vessel, but also macrocracks on the carbon monolith could be avoided. X-ray diffraction (XRD), nitrogen sorption, transmission electron microscopy (TEM), Scanning electron microscopy (SEM), mechanical stability test, and conductivity test were used to characterize the mesoporous carbon monolith, which exhibits the improved long-range mesostructured order, higher mechanically stable mesostructure, and superior conductivity, compared with mesoporous carbon monolith synthesized from SBA-15 monolith. (c) 2005 Elsevier Inc. All rights reserved.
引用
收藏
页码:136 / 142
页数:7
相关论文
共 34 条
[1]   Monolithic mesoporous silica templated by microemulsion liquid crystals [J].
Feng, PY ;
Bu, XH ;
Stucky, GD ;
Pine, DJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (05) :994-995
[2]   Synthesis of ordered nanoporous carbons of tunable mesopore size by templating SBA-15 silica materials [J].
Fuertes, AB .
MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 67 (2-3) :273-281
[3]  
Göltner CG, 1998, ANGEW CHEM INT EDIT, V37, P613, DOI 10.1002/(SICI)1521-3773(19980316)37:5<613::AID-ANIE613>3.0.CO
[4]  
2-G
[5]   Direct preparation of nanoporous carbon by nanocasting [J].
Han, BH ;
Zhou, WZ ;
Sayari, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (12) :3444-3445
[6]   Simple silica-particle template synthesis of mesoporous carbons [J].
Han, SJ ;
Hyeon, T .
CHEMICAL COMMUNICATIONS, 1999, (19) :1955-1956
[7]   Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles [J].
Joo, SH ;
Choi, SJ ;
Oh, I ;
Kwak, J ;
Liu, Z ;
Terasaki, O ;
Ryoo, R .
NATURE, 2001, 412 (6843) :169-172
[8]   Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure [J].
Jun, S ;
Joo, SH ;
Ryoo, R ;
Kruk, M ;
Jaroniec, M ;
Liu, Z ;
Ohsuna, T ;
Terasaki, O .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) :10712-10713
[9]   Reversible replication between ordered mesoporous silica and mesoporous carbon [J].
Kang, M ;
Yi, SH ;
Lee, HI ;
Yie, JE ;
Kim, JM .
CHEMICAL COMMUNICATIONS, 2002, (17) :1944-1945
[10]   Fabrication of nanocapsules with Au particles trapped inside carbon and silica nanoporous shells [J].
Kim, JY ;
Yoon, SB ;
Yu, JS .
CHEMICAL COMMUNICATIONS, 2003, (06) :790-791