Sorption-desorption behavior of bispyrazolato-copper(II) 1D coordination polymers

被引：180

作者：

Cingolani, A

Galli, S

Masciocchi, N

Pandolfo, L

Pettinari, C

Sironi, A

机构：

[1] Univ Insubria, Dipartimento Sci Chim & Ambientali, I-22100 Como, Italy

[2] Univ Camerino, Dipartimento Sci Chim, I-62032 Camerino, MC, Italy

[3] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy

[4] Univ Milan, Dipartimenot Chim Structt & Stereochim Inorgan, I-20123 Milan, Italy

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 17期

关键词：

D O I：

10.1021/ja050856+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new polycrystalline vapochromic polymorph of the one-dimensional copper bispyrazolate polymer reversibly and selectively absorbs a number of small molecules; the crystal structures of the anhydrous and fully hydrated species, determined by powder diffraction methods, are markedly different despite their simple, fast, and reversible interconversion. Copyright © 2005 American Chemical Society.

引用

收藏

页码：6144 / 6145

页数：2

相关论文

共 16 条

[1] Mineralomimetic sodalite- and muscovite-type coordination frameworks. Dynamic crystal-to-crystal interconversion processes sensitive to ion pair recognition [J].

Barea, E ;

Navarro, JAR ;

Salas, JM ;

Masciocchi, N ;

Galli, S ;

Sironi, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (10) :3014-3015

[2] Crystal engineering - nucleation, the key step [J].

Davey, RJ ;

Allen, K ;

Blagden, N ;

Cross, WI ;

Lieberman, HF ;

Quayle, MJ ;

Righini, S ;

Seton, L ;

Tiddy, GJT .

CRYSTENGCOMM, 2002, 4 :257-264

[3] METAL PYRAZOLATE POLYMERS .2. SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF [CU(4-CL PYRAZOLATE)2)X, (CU(4-BR PYRAZOLATE)2)X, (CU(4-ME PYRAZOLATE)2)X, (CU(4-H PYRAZOLATE)2)X POLYMERS [J].

EHLERT, MK ;

RETTIG, SJ ;

STORR, A ;

THOMPSON, RC ;

TROTTER, J .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1991, 69 (03) :432-439

[4] A detailed study of the vapochromic behavior of {Tl[Au(C6Cl5)2]}n [J].

Fernández, EJ ;

López-De-Luzuriaga, JM ;

Monge, M ;

Montiel, M ;

Olmos, ME ;

Pérez, J ;

Laguna, A ;

Mendizabal, F ;

Mohamed, AA ;

Fackler, JP .

INORGANIC CHEMISTRY, 2004, 43 (12) :3573-3581

[5] Non-classical Fe-II spin-crossover behaviour leading to an unprecedented extremely large apparent thermal hysteresis of 270 K: Application for displays [J].

Garcia, Y ;

vanKoningsbruggen, PJ ;

Codjovi, E ;

Lapouyade, R ;

Kahn, O ;

Rabardel, L .

JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (06) :857-858

[6]

GASPARAC R, 2000, EFC BOOK SERIES, V28, P20

[7] Spin crossover phenomena in Fe(II) complexes [J].

Gütlich, P ;

Garcia, Y ;

Goodwin, HA .

CHEMICAL SOCIETY REVIEWS, 2000, 29 (06) :419-427

[8] SPIN TRANSITION MOLECULAR MATERIALS FOR DISPLAYS AND DATA RECORDING [J].

KAHN, O ;

KROBER, J ;

JAY, C .

ADVANCED MATERIALS, 1992, 4 (11) :718-728

[9]

LaMonica G, 1997, PROG INORG CHEM, V46, P151

[10] Metal pyrazolato complexes. Synthesis, characterization, and X-ray powder diffraction studies of group 12 coordination polymers [J].

Masciocchi, N ;

Ardizzoia, GA ;

Maspero, A ;

LaMonica, G ;

Sironi, A .

INORGANIC CHEMISTRY, 1999, 38 (16) :3657-3664