Preparation and nonlinear optical studies of a novel thermal stable polymer containing azo chromophores in the side chain

被引：67
|
作者：
Chen, Xingbo
Zhang, Jingjing
Zhang, Haibo
Jiang, Zhenhua
Shi, Guang
Li, Yunbo
Song, Yinglin
机构：
[1] Jilin Univ, Alan G MacDiarmid Inst, Dept Chem, Changchun 130012, Peoples R China
[2] Harbin Inst Technol, Dept Appl Sci, Harbin 150001, Peoples R China
来源：
DYES AND PIGMENTS | 2008年 / 77卷 / 01期
关键词：
azo polymer; chromophore; poly(aryl ether); third-order nonlinear optics; Z-scan;
D O I：
10.1016/j.dyepig.2007.05.006
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A novel bisfluoro NLO chromophore monomer, 4-[(4-cyanophenyl)diazenyl]phenyl-2,6-difluorobenzoate was synthesized via a two-step synthetic procedure. Azobenzene-functionalized poly(aryl ether) (azo-PAE) was prepared via a nucleophilic aromatic substitution polycondensation based on this monomer. The obtained polymer was characterized and evaluated by FT-IR, UV-vis, H-1 NMR, DSC and TGA. The third-order NLO coefficient was measured by Z-scan technique. The results showed the azo-PAE has high glass transition temperature, good thermal stability and large third-order nonlinear susceptibility. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：223 / 228
页数：6
相关论文
共 50 条
  • [21] Preparation of polymer optical fibers doped with nonlinear optical active organic chromophores
    Peng, GD
    Li, ADQ
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2001, 39 (15) : 1794 - 1801
  • [22] Preparation and Optical Properties of Azo Polymer Containing Benzothiazole Group
    Wu, Guang-yu
    Wang, Hai-bo
    Qu, Feng-xian
    PROGRESS IN FUNCTIONAL MATERIALS, 2013, 538 : 11 - 14
  • [23] Functionalized polymers with strong push-pull azo chromophores in side chain for optical application
    Derkowska-Zielinska, B.
    Skowronski, L.
    Sypniewska, M.
    Chomicki, D.
    Smokal, V.
    Kharchenko, O.
    Naparty, M.
    Krupka, O.
    OPTICAL MATERIALS, 2018, 85 : 391 - 398
  • [24] Survey of enhanced, thermally stable, and soluble second-order nonlinear optical azo chromophores
    Matsui, M
    Suzuki, M
    Hayashi, M
    Funabiki, K
    Ishigure, Y
    Doke, Y
    Shiozaki, H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2003, 76 (03) : 607 - 612
  • [25] A NOVEL SYNTHETIC METHOD FOR THE INCORPORATION OF HIGHLY EFFICIENT NONLINEAR-OPTICAL CHROMOPHORES INTO SIDE-CHAIN POLYMERS
    DROST, KJ
    JEN, AKY
    RAO, VP
    CAI, YM
    CALDWELL, BJ
    DRZEWINSKI, MA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 41 - IEC
  • [26] Synthesis and Photophysical Properties of Soluble Polyimides and Polyquinazolones Containing Side-Chain Chalcones or Azo Chromophores
    Nosova, G. I.
    Abramov, I. G.
    Solovskaya, N. A.
    Smirnov, N. N.
    Zhukova, E. V.
    Lyskov, V. B.
    Dobrokhotov, O. V.
    Aleksandrova, E. L.
    Maslyanitsyn, I. A.
    Shigorin, V. D.
    Yakimanskii, A. V.
    POLYMER SCIENCE SERIES B, 2011, 53 (1-2) : 73 - 88
  • [27] Synthesis and photophysical properties of soluble polyimides and polyquinazolones containing side-chain chalcones or azo chromophores
    G. I. Nosova
    I. G. Abramov
    N. A. Solovskaya
    N. N. Smirnov
    E. V. Zhukova
    V. B. Lyskov
    O. V. Dobrokhotov
    E. L. Aleksandrova
    I. A. Maslyanitsyn
    V. D. Shigorin
    A. V. Yakimanskii
    Polymer Science Series B, 2011, 53 : 73 - 88
  • [28] Synthesis of nonlinear optical side-chain polymers containing the carbazolyldinitrophenylhydrazone moiety by polymer reaction
    Kim, DW
    Park, SY
    Hong, SI
    POLYMER JOURNAL, 1999, 31 (01) : 55 - 60
  • [29] Synthesis of Nonlinear Optical Side-Chain Polymers Containing the Carbazolyldinitrophenylhydrazone Moiety by Polymer Reaction
    Dong Wook Kim
    Soo Young Park
    Sung Il Hong
    Polymer Journal, 1999, 31 : 55 - 60
  • [30] Preparation and Multiple Responsiveness of Copolymers of PNIPAM Containing Azo Pyridine in Side Chain
    Xue, Xiao-qiang
    Qing, Feng
    Huang, Wen-yan
    Yang, Hong-jun
    Jiang, Qi-min
    Zhou, Lei
    Jiang, Bi-biao
    ACTA POLYMERICA SINICA, 2018, (09): : 1175 - 1183
12345