Preparation and nonlinear optical studies of a novel thermal stable polymer containing azo chromophores in the side chain

被引：67
作者：
Chen, Xingbo
Zhang, Jingjing
Zhang, Haibo
Jiang, Zhenhua
Shi, Guang
Li, Yunbo
Song, Yinglin
机构：
[1] Jilin Univ, Alan G MacDiarmid Inst, Dept Chem, Changchun 130012, Peoples R China
[2] Harbin Inst Technol, Dept Appl Sci, Harbin 150001, Peoples R China
来源：
DYES AND PIGMENTS | 2008年 / 77卷 / 01期
关键词：
azo polymer; chromophore; poly(aryl ether); third-order nonlinear optics; Z-scan;
D O I：
10.1016/j.dyepig.2007.05.006
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A novel bisfluoro NLO chromophore monomer, 4-[(4-cyanophenyl)diazenyl]phenyl-2,6-difluorobenzoate was synthesized via a two-step synthetic procedure. Azobenzene-functionalized poly(aryl ether) (azo-PAE) was prepared via a nucleophilic aromatic substitution polycondensation based on this monomer. The obtained polymer was characterized and evaluated by FT-IR, UV-vis, H-1 NMR, DSC and TGA. The third-order NLO coefficient was measured by Z-scan technique. The results showed the azo-PAE has high glass transition temperature, good thermal stability and large third-order nonlinear susceptibility. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：223 / 228
页数：6
相关论文
共 21 条
  • [1] SYNTHESIS AND PROPERTIES OF POLYARYLETHERKETONES
    ATTWOOD, TE
    DAWSON, PC
    FREEMAN, JL
    HOY, LRJ
    ROSE, JB
    STANILAND, PA
    [J]. POLYMER, 1981, 22 (08) : 1096 - 1103
  • [2] Chérioux F, 2002, ADV FUNCT MATER, V12, P203, DOI 10.1002/1616-3028(200203)12:3<203::AID-ADFM203>3.0.CO
  • [3] 2-L
  • [4] New third-order nonlinear polymers functionalized with Disperse Red and Disperse Orange chromophores with increased stability
    Cherioux, F
    Audebert, P
    Maillotte, H
    Grossard, L
    Hernandez, FE
    Lacourt, A
    [J]. CHEMISTRY OF MATERIALS, 1997, 9 (12) : 2921 - 2927
  • [5] Z-scan measurements of third-order optical non-linearities in poly(phenylacetylenes)
    Falconieri, M
    D'Amato, R
    Furlani, A
    Russo, MV
    [J]. SYNTHETIC METALS, 2001, 124 (01) : 217 - 219
  • [6] Synthesis and the third-order non-linear optical properties of new azobenzene-containing side-chain polymers
    Li, Najun
    Lu, Jianmei
    Xu, Qingfeng
    Wang, Lihua
    [J]. OPTICAL MATERIALS, 2006, 28 (12) : 1412 - 1416
  • [7] Nonlinearly optical-optical isomerization cycle in azobenzene liquid crystal polymers
    Liang, ZC
    Ming, H
    Wang, P
    Zhang, JY
    Xie, JP
    Zhang, QJ
    [J]. JOURNAL OF APPLIED PHYSICS, 2001, 90 (12) : 5866 - 5870
  • [8] Two new poly(arylene ether sulfone)s containing second-order nonlinear optical chromophores
    Lu, ZQ
    Li, J
    Hua, JL
    Li, X
    Qin, JG
    Qin, AJ
    Ye, C
    [J]. SYNTHETIC METALS, 2005, 152 (1-3) : 217 - 220
  • [9] Two novel fluorinated poly(arylene ether)s with pendant chromophores for second-order nonlinear optical application
    Lu, ZQ
    Shao, P
    Li, J
    Hua, JL
    Qin, JG
    Qin, AJ
    Ye, C
    [J]. MACROMOLECULES, 2004, 37 (19) : 7089 - 7096
  • [10] POLYIMIDES DERIVED FROM 2,2'-BIS(TRIFLUOROMETHYL)-4,4'-DIAMINOBIPHENYL .4. OPTICAL-PROPERTIES OF FLUORINATED POLYIMIDES FOR OPTOELECTRONIC COMPONENTS
    MATSUURA, T
    ANDO, S
    SASAKI, S
    YAMAMOTO, F
    [J]. MACROMOLECULES, 1994, 27 (22) : 6665 - 6670
123