Highly selective ion probe for Al3+ based on Au(I)•••Au(I) interactions in a bis-alkynyl calix[4]arene Au(I) isocyanide scaffold

被引:97
作者
Hau, Franky Ka-Wah
He, Xiaoming
Lam, Wai Han
Yam, Vivian Wing-Wah [1 ]
机构
[1] Univ Hong Kong, Inst Mol Funct Mat, Areas Excellence Scheme, Univ Grants Comm, Hong Kong, Hong Kong, Peoples R China
关键词
METAL-METAL INTERACTIONS; RAY CRYSTAL-STRUCTURES; RIGID-ROD POLYMERS; GOLD(I) COMPLEXES; AUROPHILIC INTERACTIONS; ALUMINUM ACCUMULATION; LUMINESCENT GOLD(I); DESIGN; CHEMISTRY; MESOPHASE;
D O I
10.1039/c1cc12677f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A bis-alkynyl calix[4] arene Au(I) isocyanide complex has been synthesized and demonstrated to be a selective ion probe for Al3+ based on Au(I)center dot center dot center dot Au(I) interactions.
引用
收藏
页码:8778 / 8780
页数:3
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