Coordination-assisted, transition-metal-catalyzed enantioselective desymmetric C-H functionalization

被引：37

作者：

Yu, Xin ^{[1
]}

Zhang, Zhuo-Zhuo ^{[2
]}

Niu, Jun-Long ^{[3
]}

Shi, Bing-Feng ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

[2] Chengdu Univ, Sch Food & Biol Engn, Chengdu 610106, Sichuan, Peoples R China

[3] Zhengzhou Univ, Coll Chem, Green Catalysis Ctr, Zhengzhou 450001, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2022年 / 9卷 / 05期

基金：

中国博士后科学基金;

关键词：

PLANAR CHIRAL FERROCENES; C(SP(3))-H BONDS; ASYMMETRIC-SYNTHESIS; ALIPHATIC AMIDES; NATURAL-PRODUCTS; ACTIVATION; ARYLATION; LIGANDS; BORYLATION; ALKYLATION;

D O I：

10.1039/d1qo01884a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Transition-metal-catalyzed asymmetric C-H functionalization has gradually emerged as a powerful tool for the creation of structural and chiral complexity in an atom- and step-economical fashion. The nature of this strategy provides a variety of methodologies to overcome the limitation of enantioselective desymmetrization caused by the synthesis of preformed multifunctional symmetric substrates. This review aims to summarise recent advances in transition-metal-catalyzed enantioselective desymmetric C-H functionalization reactions via coordination-assisted metal insertion, covering the literature from 2008 to June 2021. The mechanistic pathway and the modes of stereocontrol are discussed where appropriate.

引用

页码：1458 / 1484

页数：27

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