Vapor-Liquid Equilibria of Binary Mixtures Containing 1-Butanol and Hydrocarbons at 313.15 K

被引：18

作者：

Belabbaci, Aouicha ^{[1
]}

Villamanan, Rosa M. ^{[2
]}

Negadi, Latifa ^{[1
]}

Martin, Carmen M. ^{[2
]}

Kaci, Ahmed Ait ^{[3
]}

Villamanan, Miguel A. ^{[2
]}

机构：

[1] Univ Abou Bekr Belkaid Tlemcen, Lab Thermodynam Appl & Modelisat Mol, LATA2M, Tilimsen 13000, Algeria

[2] Univ Valladolid, ETS Ingn Ind, Dept Ingn Energet & Fluido Mecan, Grp Termodinam & Calibrac TERMOCAL, E-47071 Valladolid, Spain

[3] Univ Sci & Technol Houari Boumed, Lab Thermodynam & Modelisat Mol, El Alia 16111, Bab Ezzouar, Algeria

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2012年 / 57卷 / 01期

关键词：

AND/OR SUBSTITUTION HYDROCARBONS; OCTANE-ENHANCING ADDITIVES; ETHER PLUS CYCLOHEXANE; TERNARY MIXTURES; PRESSURE MEASUREMENTS; DIISOPROPYL ETHER; NONPOLAR MIXTURES; SYSTEMS; HEPTANE; THERMODYNAMICS;

D O I：

10.1021/je200840e

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Total pressure measurements made at 313.15 K by the static method for five binary mixtures 1-butanol + heptane, 2,2,4-trimethylpentane, dodecane, cyclohexane, and methylbenzene are presented. Data reduction by Barker's method provides correlations for G(E), using the four-parameter Margules equation; also the Wilson, nonrandom two-liquid (NRTL), and universal quasichemical activity coefficient (UNIQUAC) models have been used for fitting binary systems. The five investigated mixtures exhibit a positive deviation from ideality. No azeotrope has been detected for 1-butanol + dodecane, and the other systems show positive azeotropy. Good results are obtained in the prediction of total pressure for these systems.

引用

页码：114 / 119

页数：6

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