Self-assembly and characterisation of grid-type iron(II), cobalt(II) and zinc(II) complexes

被引：33

作者：

Patroniak, V

Baxter, PNW

Lehn, JM

Kubicki, M

Nissinen, M

Rissanen, K

机构：

[1] Univ Strasbourg, ISIS, F-67083 Strasbourg, France

[2] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland

[3] Univ Jyvaskyla, Dept Chem, SF-40351 Jyvaskyla, Finland

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 22期

关键词：

grid-type complexes; iron; cobalt; zinc; supramolecular chemistry; self-assembly; BIOLOGICAL PRINCIPLES; METAL-COMPLEXES; GENERATION; ARRAYS; CAVITY; PERSPECTIVES; ORGANIZATION; RECOGNITION; LIGANDS; DEVICES;

D O I：

10.1002/ejic.200300330

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the ligands 5 and 6, containing two tridentate binding units, with iron(ii), cobalt(ii) and zinc(ii) leads to the self-assembly of supramolecular architectures of [2 x 2] grid type containing four ions in octahedral coordination sites. The grid-type structures have been assigned on the basis of the spectroscopic data in solution, and confirmed in the solid state in the case of complexes 6b and 6c by X-ray crystallography. The latter study revealed that each metal ion is situated in a distorted octahedral coordination environment comprising two N,N,O ligand donor sets.

引用

页码：4001 / 4009

页数：9

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