Interface Tension-Induced Synthesis of Monodispersed Mesoporous Carbon Hemispheres

被引:131
作者
Fang, Yin [1 ,2 ,3 ]
Lv, Yingying [1 ,2 ,3 ]
Gong, Feng [4 ]
Wu, Zhangxiong [5 ]
Li, Xiaomin [1 ,2 ,3 ]
Zhu, Hongwei [1 ,2 ,3 ]
Zhou, Lei [1 ,2 ,3 ]
Yao, Chi [1 ,2 ,3 ]
Zhang, Fan [1 ,2 ,3 ]
Zheng, Gengfeng [1 ,2 ,3 ]
Zhao, Dongyuan [1 ,2 ,3 ]
机构
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[3] Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China
[4] Natl Univ Singapore, Dept Mech Engn, Singapore 117576, Singapore
[5] Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia
关键词
SILICA NANOPARTICLES; JANUS PARTICLES; NANOSPHERES; NANOSTRUCTURES; CHEMISTRY; MECHANISM; DELIVERY; DESIGN; GROWTH; SHELL;
D O I
10.1021/jacs.5b01522
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Here we report a novel interface tension-induced shrinkage approach to realize the synthesis of monodispersed asymmetrical mesoporous carbon nanohemispheres. We demonstrate that the products exhibit very uniform hemispherical morphology (130 x 60 nm) and are full of ordered mesopores, endowing them high surface areas and uniform pore sizes. These monodispersed mesoporous carbon hemispheres display excellent dispersibility in water for a long period without any aggregation. Moreover, a brand new feature of the mesoporous carbon materials has been observed for the first time: these monodispersed mesoporous carbon hemispheres show excellent thermal generation property under a NIR irradiation.
引用
收藏
页码:2808 / 2811
页数:4
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