meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) dibromidedihydrate

被引：3
作者：
He, XiuLi [1 ]
Shi, Feifei [1 ]
Lu, Yonghong [1 ]
机构：
[1] Southeast Univ, Ordered Matter Sci Res Ctr, Coll Chem & Chem Engn, Nanjing 210096, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
CRYSTAL-STRUCTURE; COMPLEXES;
D O I：
10.1107/S1600536810033714
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [Ni(C16H32N4)]Br-2 center dot 2H(2)O, consists of one half [Ni(C16H32N4)](2+) cation, one Br anion and one water molecule of crystallization. The Ni II ion lies on an inversion centre in a square-planar environment formed by the four macrocyclic ligand N atoms. In the crystal structure, the cations, anions and water molecules are linked via intermolecular N-H center dot center dot center dot Br and O-H center dot center dot center dot Br hydrogen bonds, forming discrete chains with set-graph motif D(2)D-2(2)(7)D-2(1)(3)D-3(2)(8). The water molecules and Br- ions are linked with set-graph motif R-4(2)(8).
引用
收藏
页码：M1339 / U1521
页数：9
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