meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) dibromidedihydrate

被引：3
作者：
He, XiuLi [1 ]
Shi, Feifei [1 ]
Lu, Yonghong [1 ]
机构：
[1] Southeast Univ, Ordered Matter Sci Res Ctr, Coll Chem & Chem Engn, Nanjing 210096, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
CRYSTAL-STRUCTURE; COMPLEXES;
D O I：
10.1107/S1600536810033714
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [Ni(C16H32N4)]Br-2 center dot 2H(2)O, consists of one half [Ni(C16H32N4)](2+) cation, one Br anion and one water molecule of crystallization. The Ni II ion lies on an inversion centre in a square-planar environment formed by the four macrocyclic ligand N atoms. In the crystal structure, the cations, anions and water molecules are linked via intermolecular N-H center dot center dot center dot Br and O-H center dot center dot center dot Br hydrogen bonds, forming discrete chains with set-graph motif D(2)D-2(2)(7)D-2(1)(3)D-3(2)(8). The water molecules and Br- ions are linked with set-graph motif R-4(2)(8).
引用
收藏
页码：M1339 / U1521
页数：9
相关论文
共 49 条
  • [21] Synthesis and x-ray crystal structure of meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1,8-di-(1-methyl-naphthalene).
    Haines, RI
    Hutchings, DR
    MOLECULES, 2003, 8 (02) : 243 - 250
  • [22] (3,5,7,7,12,14,14-Heptamethyl-1,4,8,11-tetraazacyclotetradec-4-11-diene)nickel(II) revisited and some (2,5,5,7,12,12,14-heptamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) compounds
    Curtis, Neil F.
    Wikaira, Jan
    Butcher, Raymond
    INORGANICA CHIMICA ACTA, 2015, 436 : 103 - 117
  • [23] μ-Actetato-1:2κ2O/O′-tribromido-2κ3Br-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene-1κ4N)dizinc(II)
    Li, HuaFeng
    Shi, FeiFei
    Rong, Rong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1338 - U1512
  • [24] Synthesis, characterization, and crystal structure of an iron(II) 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane macrocyclic complex
    Ishiruji, Fabiana H. O.
    Evans, David J.
    Hasegawa, Tai
    Nunes, Fabio S.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2006, 36 (06) : 365 - 369
  • [25] Synthesis, characterization, and crystal structure of an iron(II) 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane macrocyclic complex
    Fabiana H. O. Ishiruji
    David J. Evans
    Tai Hasegawa
    Fábio S. Nunes
    Journal of Chemical Crystallography, 2006, 36 : 365 - 369
  • [26] Crystal structures of two (5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)iron(III) complexes
    Clendening, Reese A.
    Zeller, Matthias
    Ren, Tong
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2019, 75 : 1509 - +
  • [27] Synthesis and Crystal Structure of an Ion-pair Compound: [H2（teta）]2+·[Ni（CN）4]2-·2H2O （teta = Meso-5,7,7,12,14,14-hexamethyl- 1,4,8,11-tetraazacyclotetradecane）
    丁建刚
    耿飞
    李宝龙
    张勇
    Chinese Journal of Structural Chemistry, 2006, (01) : 25 - 28
  • [28] Synthesis, crystal structure and magnetic property of a supermolecule (H2teta)2{[Ni(teta)][Fe(CN)6]2}•17H2O(teta=5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)
    Yuan, AH
    Shen, XP
    Zhou, H
    Lu, LD
    ACTA CHIMICA SINICA, 2005, 63 (19) : 1795 - 1801
  • [29] Crystal structure of a copper(II) complex with 2,3-dioxo-5,6:13,14-dibenzo-9-methyl-7-12-bis(ethoxycarbonyl)-1,4,8,11-tetraazacyclotetradeca-7,11-diene
    Gao, EQ
    Nie, Y
    Sun, HY
    Liao, DZ
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2001, 20 (03) : 183 - 186
  • [30] Cr(III)-HMC (HMC=5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane) Alkynyl Complexes: Preparation and Emission Properties
    Tyler, Sarah F.
    Judkins, Eileen C.
    Song, You
    Cao, Fan
    McMillin, David R.
    Fanwick, Phillip E.
    Ren, Tong
    INORGANIC CHEMISTRY, 2016, 55 (17) : 8736 - 8743
12345