meso-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)nickel(II) dibromidedihydrate

被引：3

作者：

He, XiuLi ^{[1
]}

Shi, Feifei ^{[1
]}

Lu, Yonghong ^{[1
]}

机构：

[1] Southeast Univ, Ordered Matter Sci Res Ctr, Coll Chem & Chem Engn, Nanjing 210096, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

CRYSTAL-STRUCTURE; COMPLEXES;

D O I：

10.1107/S1600536810033714

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, [Ni(C16H32N4)]Br-2 center dot 2H(2)O, consists of one half [Ni(C16H32N4)](2+) cation, one Br anion and one water molecule of crystallization. The Ni II ion lies on an inversion centre in a square-planar environment formed by the four macrocyclic ligand N atoms. In the crystal structure, the cations, anions and water molecules are linked via intermolecular N-H center dot center dot center dot Br and O-H center dot center dot center dot Br hydrogen bonds, forming discrete chains with set-graph motif D(2)D-2(2)(7)D-2(1)(3)D-3(2)(8). The water molecules and Br- ions are linked with set-graph motif R-4(2)(8).

引用

页码：M1339 / U1521

页数：9

共 11 条

[1]

[Anonymous], 2005, CRYSTALCLEAR

[2] Delocalized TCNQ stacks in nickel and copper tetraazamacrocyclic systems [J].

Ballester, L ;

Gil, AM ;

Gutiérrez, A ;

Perpiñán, MF ;

Azcondo, MT ;

Sánchez, AE ;

Coronado, E ;

Gómez-García, CJ .

INORGANIC CHEMISTRY, 2000, 39 (13) :2837-2842

[3] PATTERNS IN HYDROGEN BONDING - FUNCTIONALITY AND GRAPH SET ANALYSIS IN CRYSTALS [J].

BERNSTEIN, J ;

DAVIS, RE ;

SHIMONI, L ;

CHANG, NL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (15) :1555-1573

[4] CONVENIENT SYNTHESIS OF TETRA-AZA-MACROCYCLIC LIGANDS TRANS-[14]-DIENE, TET A, AND TET B [J].

HAY, RW ;

LAWRANCE, GA ;

CURTIS, NF .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (06) :591-593

[5]

HEINLEIN T, 1985, Z KRISTALLOGR, V170, P70

[6] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[7] Crystal structure and spectroscopic properties of a new five-coordinate mixed-ligand nickel(II) complex with a macrocyclic ligand:: [Ni(trans[14]diene)SCN]ClO4 (trans[14]diene=5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) [J].

Shen, HY ;

Liao, DZ ;

Jiang, ZH ;

Yan, SP .

TRANSITION METAL CHEMISTRY, 1999, 24 (05) :581-583

[8] SYNTHESIS AND STRUCTURE OF TRANS-SEC,RAC-[COL(CH3)(H2O)](CF3SO3)2 - L = 5,7,7,12,14,14-HEXAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECA-4,11-DIENE - STERIC SELECTIVITY IN ALKYL RADICAL METAL RADICAL REACTIONS [J].

SZALDA, DJ ;

SCHWARZ, CL ;

CREUTZ, C .

INORGANIC CHEMISTRY, 1991, 30 (03) :586-588

[9] Syntheses, crystal structures and characterizations of tetraazamacrocyclic complexes meso-[Ni(1,7-CT)]I2 and dl-[Ni(1,7-CT)][Fe(CN)5NO]•H2O [J].

Wang, Wen-Bo ;

Yang, Li-Xin ;

Yu, Liang-Cai ;

Song, Chun-Xia ;

Wu, Shu-Ying .

JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (04) :528-539

[10] SOME CYCLIC TETRA-AMINES AND THEIR METAL-ION COMPLEXES .6. CRYSTAL STRUCTURE OF ACETATO-C-RAC-(5,7,7,12,14,14-HEXAMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE)NICKEL(II)PERCHLORATE [J].

WHIMP, PO ;

CURTIS, NF ;

BAILEY, MF .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (11) :1956-&

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