Synthesis and Photoelectrochemical Properties of Polypyridyl Ruthenium(II) Complexes Containing 1,3,4-Oxadiazole

被引：0

作者：

Li Xiang-Hong ^{[1
]}

机构：

[1] S Cent Univ Nationalities, Inst Chem & Mat, Wuhan 430074, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 26卷 / 08期

关键词：

oxadiazole moieties; amphiphilic polypyridyl ruthenium(II) complexes; photoelectric conversion; CHARGE-TRANSFER; SENSITIZERS; DESIGN; LIGHT;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new amphiphilic ruthenium complexes with new bipyridyl ligands, Ru(CPOD)(dcbpy)(NCS)(2)(Ru-I) and Ru(DPOD)(dcbpy)(NCS)(2)(Ru-2) (CPOD=4-carboxy-4'-[2-(4-nonyloxyphenyl)-5-phenyl-oxadiazorl]-2,2' bipyridine, DPOD =4,4' -di [2-(4-nonyloxyphenyl)-5-phenyl-1,3,4-oxadiazoyl]-2,2' -bipyridine, dcbpy =4,4' - dicarboxy-2,2'-bipyridine), were synthesized and characterized by IR spectra, cyclic voltammetry, UV-Vis spectra, elemental analysis and I-V curves. They exhibit good MLCT absorptions and high molar extinction coefficients (similar to 1.43 x 10(4) L . mol(-1) . cm(-1) at 555 nm). The spectroscopic and electrochemical measurements show that the excited states of these complexes match the conduction band of titanium dioxide. They were used as sensitzers for dye-sensitized solar cells and their photoelectric conversion efficiencies are nearly 2.4%.

引用

页码：1389 / 1393

页数：5

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