Dipole moments and intermolecular association of some carbonyl compounds in nonpolar solvents

被引：19

作者：

Gilani, AG ^{[1
]}

Mamaghani, M ^{[1
]}

Anbir, L ^{[1
]}

机构：

[1] Gilan Univ, Fac Sci, Dept Chem, Rasht, Iran

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2003年 / 32卷 / 07期

关键词：

carbonyl compounds; dielectric constant; dipole moment; molecular associations; acetone; acetophenone; benzophenone; cyclohexane;

D O I：

10.1023/A:1026344422952

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The aggregation of some aldehydes in nonpolar solvents was investigated using the static dielectric method. The molecular association of acetone and two of its derivatives ( acetophenone and benzophenone) in cyclohexane solvent were also investigated by this method. Analysis of the static dielectric data for solution of these materials indicated a high molecular association. It was found that benzaldehyde and its derivatives have a strong tendency for antiparallel molecular association, whereas acetone and its derivatives have a tendency for parallel alignment. The experimental results show that there is a sensitive relationship between the molecular association and molecular structure of these materials. The influence of solvent on the molecular association of the solute molecules was studied and compared.

引用

页码：625 / 636

页数：12

共 22 条

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[Anonymous], THEORY ELECT POLARIS

[2]

*CRC, 1978, HDB CHEM PHYSICS

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