Coupled CFD analysis of size distributions on indoor secondary organic aerosol derived from ozone/limonene reactions

被引:13
|
作者
Ito, Kazuhide [1 ]
Harashima, Hiroshi [2 ]
机构
[1] Kyushu Univ, Interdisciplinary Grad Sch Engn Sci, Fukuoka 8168580, Japan
[2] Obayashi Co Ltd, Fukuoka, Japan
关键词
Indoor environment; CFD; Chemical reaction; Secondary organic aerosol (SOA); NUCLEATION MODE PARTICLES; OZONE-INITIATED REACTIONS; GAS-PHASE REACTIONS; RATES; MONOTERPENES; COAGULATION; POLLUTANTS; EMISSIONS; TRANSPORT; PRODUCTS;
D O I
10.1016/j.buildenv.2010.10.003
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
Recently theoretical analysis and experiment have been initiated to investigate the generation of secondary organic aerosols (SOA) by chemical reactions in indoor air In particular It has been confirmed that SOA are generated by the reaction of ozone with various terpenoids The overarching goal of this work was to better understand ozone VOC (volatile organic compounds) and generated SOA distributions within rooms We carried out cylindrical test chamber experiments to measure SOA generation from the chemical reaction of ozone and limonene and discussed numerical models to describe it. In this paper we propose a method for predicting the particle size distribution of SOA generated by ozone and limonene chemical reactions in air In particular we discuss an analytical method that Involves a sectional modeling approach governing equations of SOA Although the changes in particle size distribution in a 40-section model were reproduced to a certain extent rigorous modeling for the generation and growth of SOA and an increased number of sections are needed for improvement of prediction accuracy (C) 2010 Elsevier Ltd All rights reserved
引用
收藏
页码:711 / 718
页数:8
相关论文
共 50 条
  • [1] The effects of ozone/limonene reactions on indoor secondary organic aerosols
    Sarwar, Golam
    Corsi, Richard
    ATMOSPHERIC ENVIRONMENT, 2007, 41 (05) : 959 - 973
  • [2] Predicting the evolution of secondary organic aerosol (SOA) size distributions due to limonene ozonolysis in indoor environments
    Youssefi, Somayeh
    Waring, Michael S.
    BUILDING AND ENVIRONMENT, 2016, 108 : 252 - 262
  • [3] Indoor Secondary Organic Aerosol Formation Initiated from Reactions between Ozone and Surface-Sorbed D-Limonene
    Waring, Michael S.
    Siegel, Jeffrey A.
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2013, 47 (12) : 6341 - 6348
  • [4] Fundamental Chamber Experiment on Indoor Secondary Aerosol Derived from Ozone/VOC Reactions
    Ito, Kazuhide
    Harashima, Hiroshi
    JOURNAL OF ASIAN ARCHITECTURE AND BUILDING ENGINEERING, 2008, 7 (02) : 419 - 425
  • [5] Indoor hydrogen peroxide derived from ozone/d-limonene reactions
    Li, TH
    Turpin, BJ
    Shields, HC
    Weschler, CJ
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2002, 36 (15) : 3295 - 3302
  • [6] Degradation of indoor limonene by outdoor ozone: A cascade of secondary organic aerosols
    Roesch, Carolin
    Wissenbach, Dirk K.
    Franck, Ulrich
    Wendisch, Manfred
    Schlink, Uwe
    ENVIRONMENTAL POLLUTION, 2017, 226 : 463 - 472
  • [7] Kinetic mechanism for predicting secondary organic aerosol formation from the reaction of d-limonene with ozone
    Leungsakul, S
    Jaoui, M
    Kamens, RM
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (24) : 9583 - 9594
  • [8] Nitrate radical, ozone and hydroxyl radical initiated aging of limonene secondary organic aerosol
    Ramasamy, Sathiyamurthi
    Nakayama, Tomoki
    Morino, Yu
    Imamura, Takashi
    Kajii, Yoshizumi
    Enami, Shinichi
    Sato, Kei
    ATMOSPHERIC ENVIRONMENT-X, 2021, 9
  • [9] Photodegradation of secondary organic aerosol generated from limonene oxidation by ozone studied with chemical ionization mass spectrometry
    Pan, X.
    Underwood, J. S.
    Xing, J. -H.
    Mang, S. A.
    Nizkorodov, S. A.
    ATMOSPHERIC CHEMISTRY AND PHYSICS, 2009, 9 (12) : 3851 - 3865
  • [10] Chemistry of secondary organic aerosol formation from ozone-alkene reactions.
    Ziemann, PJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U526 - U527