VIBRATIONAL STUDY OF DIPOTASSIUM ZINC BIS(DIHYDROGENDIPHOSPHATE) DIHYDRATE, K2ZN(H2P2O7)2•2H2O

被引：5
作者：
Khaoulaf, Redouane [1 ]
Ezzaafrani, Mustapha [1 ]
Ennaciri, Abdelaziz [1 ]
Harcharras, Mohammed [1 ]
Capitelli, Francesco [2 ]
机构：
[1] Univ Ibn Tofail, Dept Chem, Equipe Spect & Chim Theor, Fac Sci, Kenitra 14000, Morocco
[2] Inst Cristallog IC CNR, I-00015 Rome, Italy
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2012年 / 187卷 / 11期
关键词：
Bent POP configuration; dihydrogendiphosphates; factor group analysis; infrared spectra; Raman spectra; CRYSTAL-STRUCTURE; RAMAN-SPECTRA; H2O; NI; MN0.5NH4H2P2O7-CENTER-DOT-H2O; PYROPHOSPHATES; DIPHOSPHATES; SPECTROSCOPY; ZN; IR;
D O I：
10.1080/10426507.2012.685669
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Infrared and Raman spectra of dipotassium zinc bis(dihydrogendiphosphate) dihydrate, K2Zn(H2P2O7)(2)center dot 2H(2)O have been collected and interpreted using factor group analysis. Noncoincidence of the Raman and infrared spectra bands confirms a centrosymmetric structure for K2Zn(H2P2O7)(2)center dot 2H(2)O previously investigated by X-ray structural study, as well as the joint appearance of nu(as) POP and nu(s) POP point to a bent POP configuration.
引用
收藏
页码：1367 / 1376
页数：10
相关论文
共 26 条
[1]   Vibrational study of manganese ammonium dihydrogendiphosphate hydrated Mn0.5NH4H2P2O7•H2O [J].
Brouzi, K ;
Ennaciri, A ;
Capitelli, F ;
Valentini, V ;
Mattei, G ;
Harcharras, M .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2005, 180 (02) :545-553
[2]   CRYSTAL-GROWTH, MORPHOLOGY, STRUCTURE, AND PROPERTIES OF HNAMP2O7 CRYSTALS WHERE M=CO AND NI [J].
BYRAPPA, K ;
DUTT, BVU ;
CLEARFIELD, A ;
POOJARY, MD .
JOURNAL OF MATERIALS RESEARCH, 1994, 9 (06) :1519-1525
[3]   Crystal structure and vibrational spectroscopy of the new acidic diphosphate (NH4)2Zn(H2P2O7)2 •2 H2O [J].
Capitelli, F ;
Khaoulaf, R ;
Harcharras, M ;
Ennaciri, A ;
Habyby, SH ;
Valentini, V ;
Mattei, G ;
Bertolasi, V .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2005, 220 (01) :25-30
[4]   Two new ammonium diphosphates:: crystal structure of Mn0.5NH4H2P2O7•H2O and MnNaNH4P2O7•3 H2O [J].
Capitelli, F ;
Brouzi, K ;
Harcharras, M ;
Ennaciri, A ;
Moliterni, AGG ;
Bertolasi, V .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2004, 219 (02) :93-98
[5]  
Durif A., 1995, CRYSTAL CHEM CONDENS
[6]   New thallium diphosphate Tl2Me(H2P2O7)2• 2 H2O, Me = Mg, Mn, Co, Ni and Zn.: Synthesis, single crystal X-ray structures and powder X-ray structure of the Mg phase [J].
El Bali, Brahim ;
Capitelli, Francesco ;
Alaoui, Aziz Tahiri ;
Lachkar, Mohammed ;
da Silva, Ivan ;
Alvarez-Larena, Angel ;
Piniella, Juan F. .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2008, 223 (07) :448-455
[7]   K2M(H2P2O7)2•2H2O (M = Ni, Cu, Zn):: orthorhombic forms and Raman spectra [J].
Essehli, R ;
El Bali, B ;
Tahiri, AA ;
Lachkar, M ;
Manoun, B ;
Dusek, M ;
Fejfarova, K .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 :I120-I124
[8]   (NH4)2[Ni(H2P2O7)2(H2O)2] [J].
Essehli, R ;
Lachkar, M ;
Svoboda, I ;
Fuess, H ;
El Bali, B .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :I64-I66
[9]   (NH4)2[Co(H2P2O7)2(H2O)2] [J].
Essehli, R ;
Lachkar, M ;
Svoboda, I ;
Fuess, H ;
El Bali, B .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :I61-I63
[10]   Crystal structure and infrared spectrum of new magnesium tetra-ammonium cyclotriphosphate tetrahydrate Mg(NH4)4(P3O9)2 • 4 H2O [J].
Ezzaafrani, Mustapha ;
Ennaciri, Abdelaziz ;
Harcharras, Mohammed ;
Khaoulaf, Redouane ;
Capitelli, Francesco .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2012, 227 (03) :141-146
123