Self-assembly of a cavitand-based capsule by dynamic boronic ester formation

被引：91

作者：

Nishimura, Naoki ^{[1
]}

Kobayashi, Kenji ^{[1
]}

机构：

[1] Shizuoka Univ, Dept Chem, Fac Sci, Suruga Ku, Shizuoka 4228529, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 33期

关键词：

calixarenes; cavitands; molecular recognition; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200802293

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Be my guest: Two molecules of a cavitand tetraboronic acid and four molecules of a bis(catechol) linker quantitatively assemble into a capsule (see picture for two views), with highly selective guest-recognition, by dynamic boronic ester formation. The on/off control of capsule formation with guest encapsulation is achieved by removal/addition of methanol. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6255 / 6258

页数：4

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