Solvent-free oxidation of benzyl alcohol over chromium orthoborate

被引：19
作者：
Oeztuerk, Oemer F. [1 ]
Zuemreoglu-Karan, Birguel [1 ]
Karabulut, Solmaz [1 ]
机构：
[1] Hacettepe Univ, Dept Chem, TR-06800 Ankara, Turkey
来源：
CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 07期
关键词：
CrBO3; benzyl alcohol oxidation; heterogeneous catalysis; solvent-free catalysis; benzaldehyde;
D O I：
10.1016/j.catcom.2008.01.016
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The use of CrBO3 in the catalytic liquid phase oxidation of benzyl alcohol (BzOH) has been investigated for the first time. The reaction was performed under solvent-free conditions without employing any oxidant. Benzaldehyde (BzH), dibenzyl ether (DBzE) and benzyl benzoate (BzB) were obtained as the major reaction products. Influence of the reaction parameters (reaction time, temperature and the amount of catalyst) on the catalytic performance has been studied. A mechanism operating over acidic boron sites has been suggested. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：1644 / 1648
页数：5
相关论文
共 50 条
[31]   Solvent-free selective oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroperoxide over U3O8-supported nano-gold catalysts [J].
Choudhary, Vasant R. ;
Dumbre, Deepa K. .
APPLIED CATALYSIS A-GENERAL, 2010, 375 (02) :252-257
[32]   Solvent-free catalytic oxidation of toluene over heterogeneous CeMnOx composite oxides [J].
Chen, Gui ;
You, Kuiyi ;
Zhao, Fangfang ;
Chen, Zhenpan ;
Luo, Hean .
RESEARCH ON CHEMICAL INTERMEDIATES, 2022, 48 (06) :2593-2606
[33]   Solvent-free catalytic oxidation of toluene over heterogeneous CeMnOx composite oxides [J].
Gui Chen ;
Kuiyi You ;
Fangfang Zhao ;
Zhenpan Chen ;
Hean Luo .
Research on Chemical Intermediates, 2022, 48 :2593-2606
[34]   Au-Pd nanoparticles immobilized on TiO2 nanosheet as an active and durable catalyst for solvent-free selective oxidation of benzyl alcohol [J].
Wang, Zhe ;
Feng, Jiangjiang ;
Li, Xiaoliang ;
Oh, Rena ;
Shi, Dongdong ;
Akdim, Ouardia ;
Xia, Ming ;
Zhao, Liang ;
Huang, Xiaoyang ;
Zhang, Guojie .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2021, 588 (588) :787-794
[35]   Liquid phase oxidation of benzyl alcohol to benzaldehyde over sepiolite loaded chromium oxide catalysts [J].
Nguyen Tien Thao ;
Nguyen Thi Nhu ;
Lin, Kuen-Song .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2018, 83 :10-22
[36]   Pd catalysts supported on MnCeOx mixed oxides and their catalytic application in solvent-free aerobic oxidation of benzyl alcohol: Support composition and structure sensitivity [J].
Chen, Yuanting ;
Zheng, Huijian ;
Guo, Zhen ;
Zhou, Chunmei ;
Wang, Chuan ;
Borgna, Armando ;
Yang, Yanhui .
JOURNAL OF CATALYSIS, 2011, 283 (01) :34-44
[37]   Holey Lamellar High-Entropy Oxide as an Ultra-High-Activity Heterogeneous Catalyst for Solvent-free Aerobic Oxidation of Benzyl Alcohol [J].
Feng, Danyang ;
Dong, Yangbo ;
Zhang, Liangliang ;
Ge, Xin ;
Zhang, Wei ;
Dai, Sheng ;
Qiao, Zhen-An .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (44) :19503-19509
[38]   Investigations of supported Au-Pd nanoparticles on synthesized CeO2 with different morphologies and application in solvent-free benzyl alcohol oxidation [J].
Li, Xiaoliang ;
Feng, Jiangjiang ;
Perdjon, Michal ;
Oh, Rena ;
Zhao, Wei ;
Huang, Xiaoyang ;
Liu, Shusen .
APPLIED SURFACE SCIENCE, 2020, 505
[39]   Solvent-free efficient oxidation of benzyl alcohol on nano-Pd/Al2O3: Effect of palladium source and pH value [J].
Yuan, Haitao ;
Li, Qing ;
Liu, Zhaozhao ;
Qi, Qingyang ;
Wan, Chengzhi ;
Yin, Xia ;
Yang, Xiaojun ;
Ding, Yigang ;
Du, Zhiping .
APPLIED CATALYSIS A-GENERAL, 2023, 654
[40]   Pd Nanoparticles on Layered Double Hydroxide as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol Using Molecular Oxygen: Effect of Support Basic Properties [J].
Chen, Tao ;
Zhang, Fazhi ;
Zhu, Yue .
CATALYSIS LETTERS, 2013, 143 (02) :206-218
12345