Fully Spray-Coated Triple-Cation Perovskite Solar Cells

被引:110
作者
Bishop, James E. [1 ]
Read, Connor D. [1 ]
Smith, Joel A. [1 ]
Routledge, Thomas J. [1 ]
Lidzey, David G. [1 ]
机构
[1] Univ Sheffield, Dept Phys & Astron, Hicks Bldg,Hounsfield Rd, Sheffield S3 7RH, S Yorkshire, England
基金
英国工程与自然科学研究理事会;
关键词
HALIDE PEROVSKITES; EFFICIENT; PHOTOVOLTAICS;
D O I
10.1038/s41598-020-63674-5
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We use ultrasonic spray-coating to sequentially deposit thin films of tin oxide, a triple-cation perovskite and spiro-OMeTAD, allowing us fabricate perovskite solar cells (PSCs) with a champion reverse scan power conversion efficiency (PCE) of 19.4% on small-area substrates. We show that the use of spray-deposition permits us to rapidly (>80mms(-1)) coat 25mm x 75mm substrates that were divided into a series of devices each with an active area of 15.4 mm(2), yielding an average PCE of 10.3% and a peak PCE of 16.3%. By connecting seven 15.4 mm(2) devices in parallel on a single substrate, we create a device having an effective active area of 1.08 cm(2) and a PCE of 12.7%. This work demonstrates the possibility for spray-coating to fabricate high efficiency and low-cost perovskite solar cells at speed.
引用
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页数:8
相关论文
共 34 条
[1]  
[Anonymous], 2014, BEST RES CELL EFF
[2]   Efficient planar heterojunction mixed-halide perovskite solar cells deposited via spray-deposition [J].
Barrows, Alexander T. ;
Pearson, Andrew J. ;
Kwak, Chan Kyu ;
Dunbar, Alan D. F. ;
Buckley, Alastair R. ;
Lidzey, David G. .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (09) :2944-2950
[3]   High-Efficiency Spray-Coated Perovskite Solar Cells Utilizing Vacuum-Assisted Solution Processing [J].
Bishop, James E. ;
Smith, Joel A. ;
Greenland, Claire ;
Kumar, Vikas ;
Vaenas, Naoum ;
Game, Onkar S. ;
Routledge, Thomas J. ;
Wong-Stringer, Michael ;
Rodenburg, Cornelia ;
Lidzey, David G. .
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (46) :39428-39434
[4]   Advances in Spray-Cast Perovskite Solar Cells [J].
Bishop, James E. ;
Routledge, Thomas J. ;
Lidzey, David G. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2018, 9 (08) :1977-1984
[5]   Spray-cast multilayer perovskite solar cells with an active-area of 1.5 cm2 [J].
Bishop, James E. ;
Mohamad, David K. ;
Wong-Stringer, Michael ;
Smith, Alex ;
Lidzey, David G. .
SCIENTIFIC REPORTS, 2017, 7
[6]   Scalable Ultrasonic Spray-Processing Technique for Manufacturing Large-Area CH3NH3PbI3 Perovskite Solar Cells [J].
Chou, Li-Hui ;
Wang, Xiao-Feng ;
Osaka, Itaru ;
Wu, Chun-Guey ;
Liu, Cheng-Liang .
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (44) :38042-38050
[7]   Ultrasonic Spray-Coated Mixed Cation Perovskite Films and Solar Cells [J].
Chou, Yi-Shang ;
Chou, Li-Hui ;
Guo, An-Zhe ;
Wang, Xiao-Feng ;
Osaka, Itaru ;
Wu, Chun-Guey ;
Liu, Cheng-Liang .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (16) :14217-14224
[8]   Excitons versus free charges in organo-lead tri-halide perovskites [J].
D'Innocenzo, Valerio ;
Grancini, Giulia ;
Alcocer, Marcelo J. P. ;
Kandada, Ajay Ram Srimath ;
Stranks, Samuel D. ;
Lee, Michael M. ;
Lanzani, Guglielmo ;
Snaith, Henry J. ;
Petrozza, Annamaria .
NATURE COMMUNICATIONS, 2014, 5
[9]   High-Performance Flexible Perovskite Solar Cells by Using a Combination of Ultrasonic Spray-Coating and Low Thermal Budget Photonic Curing [J].
Das, Sanjib ;
Yang, Bin ;
Gu, Gong ;
Joshi, Pooran C. ;
Ivanov, Ilia N. ;
Rouleau, Christopher M. ;
Aytug, Tolga ;
Geohegan, David B. ;
Xiao, Kai .
ACS PHOTONICS, 2015, 2 (06) :680-686
[10]   Fully Air-Bladed High-Efficiency Perovskite Photovoltaics [J].
Ding, Jie ;
Han, Qiwei ;
Ge, Qian-Qing ;
Xue, Ding-Jiang ;
Ma, Jing-Yuan ;
Zhao, Bo-Ya ;
Chen, Yao-Xuan ;
Liu, Jie ;
Mitzi, David B. ;
Hu, Jin-Song .
JOULE, 2019, 3 (02) :402-416