Synthesis of Monocrystalline Nanoframes of Prussian Blue Analogues by Controlled Preferential Etching

被引：215

作者：

Zhang, Wei ^{[1
]}

Zhao, Yanyi ^{[1
]}

Malgras, Victor ^{[2
]}

Ji, Qingmin ^{[3
]}

Jiang, Dongmei ^{[1
]}

Qi, Ruijuan ^{[4
]}

Ariga, Katsuhiko ^{[2
]}

Yamauchi, Yusuke ^{[2
]}

Liu, Jian ^{[5
]}

Jiang, Ji-Sen ^{[1
]}

Hu, Ming ^{[1
]}

机构：

[1] East China Normal Univ, Sch Phys & Mat Sci, Shanghai 200241, Peoples R China

[2] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki, Japan

[3] Nanjing Univ Sci & Technol, Herbert Gleiter Inst Nanosci, Nanjing, Peoples R China

[4] East China Normal Univ, Key Lab Polar Mat & Devices, Shanghai 200262, Peoples R China

[5] Curtin Univ, Dept Chem Engn, Perth, WA 6845, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 29期

基金：

中国国家自然科学基金;

关键词：

alkali metals; coordination compounds; hollow nanostructures; ion insertion/extraction; surface etching; METAL-ORGANIC FRAMEWORKS; SODIUM-ION BATTERIES; CATHODE MATERIAL; NICKEL HEXACYANOFERRATE; COORDINATION POLYMERS; SUPERIOR CATHODE; CORE-SHELL; LOW-COST; INTERFACIAL SYNTHESIS; LITHIUM STORAGE;

D O I：

10.1002/anie.201600661

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal cyanide coordination compounds are recognized as promising candidates for broad applications because of their tailorable and adjustable frameworks. Developing the nanostructure of a coordination compound may be an effective way to enhance the performance of that material in application-based roles. A controllable preferential etching method is described for synthesis of monocrystalline Prussian blue analogue (PBA) nanoframes, without the use of organic additives. The PBA nanoframes show remarkable rate performance and cycling stability for sodium/lithium ion insertion/extraction.

引用

页码：8228 / 8234

页数：7

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