Corrosion Behavior of 316L Stainless Steel in Oilfield Produced Water in Presence of CO2 and Acetic Acid

被引:4
作者
Li, Ping [1 ]
Du, Min [1 ]
Hou, Jian [2 ]
Zhang, Yanli [1 ]
Fan, Lin [2 ]
Lin, Cunguo [2 ]
机构
[1] Ocean Univ China, Coll Chem & Chem Engn, Key Lab Marine Chem Theory & Technol, Minist Educ, Qingdao 266100, Peoples R China
[2] Luoyang Ship Mat Res Inst LSMRI, State Key Lab Marine Corros & Protect, Qingdao 266237, Peoples R China
来源
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2020年 / 15卷 / 05期
基金
中国国家自然科学基金;
关键词
316L stainless steel; temperature; acetic acid concentration; CO2 partial pressure; pitting corrosion; PITTING CORROSION; MILD-STEEL; LOCALIZED CORROSION; PIT INITIATION; PASSIVE FILM; TEMPERATURE; MECHANISM; GROWTH; 304-STAINLESS-STEEL; BREAKDOWN;
D O I
10.20964/2020.05.23
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
316L stainless steel has good corrosion resistance and is widely used in oilfield produced water. The environment of oilfield produced water is complicated by corrosion factors such as acetic acid, CO2, high temperature and high pressure, which easily lead to pitting corrosion. Corrosion behavior of 316L stainless steel in oilfield produced water was studied by weight loss, anode polarization curve, electrochemical impedance spectroscopy and scanning electron microscope methods. The pitting corrosion was the main behavior to 316L stainless steel in the simulated oilfield produced water. The corrosion rate increased first and then decreased with the increase of temperature and the corrosion rate was the highest at 60 degrees C. The passivation current density of 316L stainless steel was the largest at 60 degrees C, indicating that the pitting sensitivity was the strongest at 60 degrees C. When the acetic acid concentration was 1000 ppm, the corrosion rate was the largest. The pore resistance and charge transfer resistance of 316L stainless steel was the smallest when 1000 ppm acetic acid was added. The low concentration of acetic acid was more likely to destroy the passivation film. When the CO2 partial pressure was 0.1 MPa, the passivation film appeared "glitches" phenomenon, and the corrosion rate reached the maximum. The maximum pitting depth of the oilfield produced water after adding 1000 ppm acetic acid and 0.1 MPa CO2 for 72 hat 60 degrees C was 0.145 mm.
引用
收藏
页码:4287 / 4307
页数:21
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