Synthesis and crystal structure of one-dimensional chainlike coordination polymer [Ag(bix)(NO3)(H2O)]n

被引：0

作者：

Wu, YP ^{[1
]}

Wen, LL ^{[1
]}

Li, YZ ^{[1
]}

Dang, DB ^{[1
]}

Lu, ZD ^{[1
]}

Meng, QJ ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 21卷 / 11期

关键词：

silver(I) complex; crystal structure; coordination polymer;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A one-dimensional (ID) Z conformation coordination polymer, [Ag(bix)(NO3)(H2O)]n was obtained by the reaction between AgNO3 and flexible ligand of 1,4-bis(imidazol-1-ylmethyl)-benzene under hydrothermal conditions. It crystallizes in triclinic with space group P1. The crystallographic data of the compound are: a = 0.777 1(2) run, b = 1.043 4(3) nm, c = 1.082 7(3) nm, alpha = 71.403(4)degrees, beta = 80.946(5)degrees, gamma = 88.794(4)degrees. The 1D chainlike structure was connected by pi-pi interaction between phenyl rings, leading to a 2D layered network. The lattice water and the NO3- anions were involved between the layers, therefore the 2D layered structure further extended to an intricate 3D framework.

引用

页码：1759 / 1762

页数：4

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