Synthesis of graft copolymers of poly(methacrylic acid)-g-poly(ε-caprolactone) by coupling ROP and RAFT polymerizations

被引：9
作者：
Kiehl, J. [1 ,2 ]
Delaite, C. [1 ]
Bistac, S. [1 ]
Schuller, A. S. [2 ]
Farge, H. [2 ]
机构：
[1] Univ Haute Alsace, Lab Photochim & Ingn Macromol, F-68093 Mulhouse, France
[2] Mader Res, F-68200 Mulhouse, France
来源：
POLYMER | 2012年 / 53卷 / 03期
关键词：
Graft copolymers; RAFT; Anionic coordinated ROP; FRAGMENTATION CHAIN-TRANSFER; TRANSFER RADICAL POLYMERIZATION; MECHANICAL-PROPERTIES; SURFACE MODIFICATION; EPSILON-CAPROLACTONE; CALCIUM-CARBONATE; MOLECULAR-WEIGHT; CLICK CHEMISTRY; POLYMERS; POLYCAPROLACTONE;
D O I：
10.1016/j.polymer.2011.12.038
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The aim of this study was to synthesize graft copolymers of poly(methacrylic acid)-g-poly(epsilon-caprolactone) by a two-step process. In a first part, a macromonomer of 2-hydroxyethylmethacrylate-poly (epsilon-caprolactone) (HEMA-PCL) was synthesized by coordinated anionic Ring Opening Polymerization (ROP). Then graft copolymers were obtained via Reversible Addition Fragmentation chain Transfer (RAFT) copolymerization of HEMA-PCL macromonomer and methacrylic acid (MAA). This two-step synthesis is a really interesting way to adjust and control parameters such as graft density, polymerization degree, copolymer composition, graft length, in order to adapt the final graft copolymers to their future applications. The efficiency of such copolymers in dispersing calcium carbonate into an unsaturated polyester resin has been point out by viscosity measurements. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：694 / 700
页数：7
相关论文
共 42 条
  • [1] First example of the atom transfer radical polymerisation of an acidic monomer: direct synthesis of methacrylic acid copolymers in aqueous media
    Ashford, EJ
    Naldi, V
    O'Dell, R
    Billingham, NC
    Armes, SP
    [J]. CHEMICAL COMMUNICATIONS, 1999, (14) : 1285 - 1286
  • [2] Searching for more effective agents and conditions for the RAFT polymerization of MMA: Influence of dithioester substituents, solvent, and temperature
    Benaglia, M
    Rizzardo, E
    Alberti, A
    Guerra, M
    [J]. MACROMOLECULES, 2005, 38 (08) : 3129 - 3140
  • [3] Acute oral toxicity evaluation of biodegradable and pH-sensitive hydrogel based on polycaprolactone, poly(ethylene glycol) and methylacrylic acid (MAA)
    Chen, Xian
    Qian, ZhiYong
    Gou, MaLing
    Chao, GuoTao
    Zhang, YangDe
    Gu, YingChun
    Huang, MeiJuan
    Wang, JiWei
    Pan, YiFeng
    Wei, YuQuan
    Chen, JianPing
    Tu, MingJing
    [J]. JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 2008, 84A (03) : 589 - 597
  • [4] Copolymer nanosphere encapsulated CdS quantum dots prepared by RAFT copolymerization: synthesis, characterization and mechanism of formation
    Das, Paramita
    Zhong, Weiheng
    Claverie, Jerome P.
    [J]. COLLOID AND POLYMER SCIENCE, 2011, 289 (14) : 1519 - 1533
  • [5] MACROMOLECULAR ENGINEERING OF POLYLACTONES AND POLYLACTIDES .3. SYNTHESIS, CHARACTERIZATION, AND APPLICATIONS OF POLY(EPSILON-CAPROLACTONE) MACROMONOMERS
    DUBOIS, P
    JEROME, R
    TEYSSIE, P
    [J]. MACROMOLECULES, 1991, 24 (05) : 977 - 981
  • [6] SURFACE MODIFICATION AND CHARACTERIZATION OF PARTICULATE MINERAL FILLERS
    FEKETE, E
    PUKANSZKY, B
    TOTH, A
    BERTOTI, I
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1990, 135 (01) : 200 - 208
  • [7] Systematic parallel investigation of RAFT polymerizations for eight different (meth)acrylates: A basis for the designed synthesis of block and random copolymers
    Fiten, MWM
    Paulus, RM
    Schubert, US
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (17) : 3831 - 3839
  • [8] Mechanism and kinetics of RAFT-based living radical polymerizations of styrene and methyl methacrylate
    Goto, A
    Sato, K
    Tsujii, Y
    Fukuda, T
    Moad, G
    Rizzardo, E
    Thang, SH
    [J]. MACROMOLECULES, 2001, 34 (03) : 402 - 408
  • [9] New polymer synthesis by nitroxide mediated living radical polymerizations
    Hawker, CJ
    Bosman, AW
    Harth, E
    [J]. CHEMICAL REVIEWS, 2001, 101 (12) : 3661 - 3688
  • [10] Metal-catalyzed living radical polymerization
    Kamigaito, M
    Ando, T
    Sawamoto, M
    [J]. CHEMICAL REVIEWS, 2001, 101 (12) : 3689 - 3745
12345