VOLTAMMETRIC BEHAVIOR OF MEDIATOR-MODIFIED ELECTRODE BY ELECTROCHEMICAL POLYMERIZATION OF NITROXYL RADICAL PRECURSOR CONTAINING PYRROLE SIDE CHAIN

被引：12

作者：

Ono, Tetsuya ^{[1
]}

Tsunoda, Makiko ^{[1
]}

Takahashi, Shigehiro ^{[1
]}

Obata, Toshio ^{[1
]}

Sone, Takanori ^{[1
]}

Kashiwagi, Yoshitomo ^{[1
]}

机构：

[1] Ohu Univ, Sch Pharmaceut Sci, Fukushima 9638611, Japan

来源：

HETEROCYCLES | 2010年 / 81卷 / 12期

关键词：

D O I：

10.3987/COM-10-12053

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper describes the voltammetric behavior of TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl)-modified electrode prepared by the electrochemical polymerization of TEMPO-modified pyrrole. The modified electrode exhibits a symmetrical reversible redox wave at +0.7 V versus Ag/AgCl, which originates from the electron transfer between the pyrrole-polymerized layer and the electrode. The properties of the polymers on the electrode surface can be modulated by varying the applied polymerization potential. The TEMPO-modified electrode exhibits electrocatalytic activity for the oxidation of geraniol.

引用

页码：2771 / 2780

页数：10

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