Photoisomerization of Vibrationally Hot Tetramethylethylene Produced by Ultrafast Internal Conversion from the Excited State

被引：4

作者：

Sato, Motoki ^{[1
]}

Adachi, Shunsuke ^{[1
]}

Suzuki, Toshinori ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kitashirakawa Oiwakecho, Kyoto 6068502, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2016年 / 120卷 / 27期

关键词：

D O I：

10.1021/acs.jpca.6b00410

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Isomerization of tetramethylethylene (TME) following ultrafast internal conversion was investigated using time-resolved photoelectron spectroscopy with vacuum-ultraviolet probe pulses. The difference photoelectron spectrum at tau = 15 ps was reasonably well reproduced using a linear combination of static photoelectron spectra of TME and its isomers. The isomers were produced as a consequence of unimolecular reaction of vibrationally hot TME, created by internal conversion from the excited state.

引用

页码：5099 / 5102

页数：4

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