Room-temperature C-H bond alkynylation by merging cobalt and photocatalysts

被引：12

作者：

Mandal, Rajib ^{[1
]}

Barsu, Nagaraju ^{[1
]}

Garai, Bholanath ^{[1
]}

Das, Abir ^{[1
]}

Perekalin, Dmitry ^{[2
]}

Sundararaju, Basker ^{[1
]}

机构：

[1] Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India

[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Vavilova Str, Moscow, Russia

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 91期

关键词：

FUNCTIONALIZATION; ANNULATION; OXYGEN; CARBONYLATION; BROMOALKYNES; ARENES;

D O I：

10.1039/d1cc05263b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new protocol is developed for the mono- and bis-ortho-C-H alkynylation of easily accessible benzamide derivatives using alkynyl bromides at room temperature by merging cobalt and photocatalysts. The diverse reactivity of various alkynyl bromides towards the C-H alkynylation and competing C-H/N-H bond annulation reactions has been demonstrated to give the corresponding products in good yields with excellent functional group tolerance.

引用

页码：12167 / 12170

页数：4

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