Room-temperature C-H bond alkynylation by merging cobalt and photocatalysts

被引：12
|
作者：
Mandal, Rajib [1 ]
Barsu, Nagaraju [1 ]
Garai, Bholanath [1 ]
Das, Abir [1 ]
Perekalin, Dmitry [2 ]
Sundararaju, Basker [1 ]
机构：
[1] Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India
[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Vavilova Str, Moscow, Russia
来源：
CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 91期
关键词：
FUNCTIONALIZATION; ANNULATION; OXYGEN; CARBONYLATION; BROMOALKYNES; ARENES;
D O I：
10.1039/d1cc05263b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new protocol is developed for the mono- and bis-ortho-C-H alkynylation of easily accessible benzamide derivatives using alkynyl bromides at room temperature by merging cobalt and photocatalysts. The diverse reactivity of various alkynyl bromides towards the C-H alkynylation and competing C-H/N-H bond annulation reactions has been demonstrated to give the corresponding products in good yields with excellent functional group tolerance.
引用
收藏
页码：12167 / 12170
页数：4
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