Selective catalytic reduction of NO with NH3 at low temperatures over iron and manganese oxides supported on mesoporous silica

被引：175

作者：

Huang, Jihui ^{[1
]}

Tong, Zhiquan ^{[1
]}

Huang, Yan ^{[1
]}

Zhang, Junfeng ^{[1
]}

机构：

[1] Xiangtan Univ, Dept Environm Sci & Engn, Xiangtan 411105, Peoples R China

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2008年 / 78卷 / 3-4期

关键词：

SCR of NO with NH3; Mn-Fe; mesoporous silica; H2O; SO2; NITRIC-OXIDE; NITROGEN-OXIDES; SCR; MECHANISM; AMMONIA; REACTIVITY;

D O I：

10.1016/j.apcatb.2007.09.031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of catalysts of iron-manganese oxide supported on mesoporous silica (NIPS) with different Mn/Fe ratio were studied for low-temperature selective catalytic reduction (SCR) of NO with ammonia in the presence of excess oxygen. Effects of amounts of iron-manganese oxide and calcination temperatures on NO conversion were also investigated. It was found that the Mn-Fe/MPS with Mn/Fe = 1 at the calcination temperature of 673 K showed the highest activity. The results showed that this catalyst yielded 99.1% NO conversion at 433 K at a space velocity of 20,000 h(-1). H2O has no adverse impact on the activity when the SCR reaction temperature is above 413 K. In addition, the SCR activity was suppressed gradually in the presence of SO2 and H2O, while such effect was reversible after heating treatment. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：309 / 314

页数：6

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