Alumina layers deposited by atomic layer deposition followed by rapid thermal anneal were characterized. We found that the crystallization of alumina in gamma-phase occurs between 700 and 850 degrees C. Optical band gap, stress, and density were found to increase upon crystallization. Hydrogen content in alumina was characterized by ToF-SIMS and infrared spectroscopy. We found that annealing ambience has a strong influence on hydrogen concentration: oxygen favors hydrogen desorption from alumina. Finally, charge trapping in alumina was characterized by C(V) measurements. A strong correlation between hydrogen concentration and trapping was established. (C) 2011 American Vacuum Society. [DOI: 10.1116/1.3535552]