Two Zinc Architectures: A Mononuclear Complex and a 2D Wave-like Organic-inorganic Hybrid Layer

被引：0

作者：

Jin Mei-Fang ^{[1
]}

Dai Fang-Na ^{[1
]}

Sun Dao-Feng ^{[1
]}

机构：

[1] Shandong Univ, Dept Chem, Key Lab Colloid & Interface Chem, Educ Minist, Jinan 250100, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 29卷 / 12期

关键词：

supramolecular architecture; zinc; metal-organic framework; mixed organic ligands; supramolecular interactions; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; NETWORK; 1-D; ADSORPTION; DESIGN; CHAIN;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Self-assembly of Zn(NO3)(2) 6H(2)O and 2,3,5,6-tetrabromoterephthalic acid (H(2)TBTA) gave rise to two new zinc metal-organic frameworks, Zn(HTBTA)(2)(phen)(2) H2O (1) and Zn(TBTA)(1/2)(mu(2)-OH)(H2O) 0 25EtOH (2) Complex 1 is a mononuclear molecule The hydrogen bonding interactions further connect the mononuclear molecules to generate a 2D supramolecular architecture Complex 2 is a 2D organic-inorganic hybrid layer framework constructed from 1D rod-shaped secondary building units

引用

页码：1834 / 1840

页数：7

共 31 条

[1]

[Anonymous], 2000, SHELXTL 6 10

[2]

Bourne SA, 2001, ANGEW CHEM INT EDIT, V40, P2111, DOI 10.1002/1521-3773(20010601)40:11<2111::AID-ANIE2111>3.0.CO

[3]

2-F

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