Recent progress in organophotoredox reaction

被引：35

作者：

Liu, Qiping ^{[1
]}

Huo, Congde ^{[1
]}

Fu, Ying ^{[1
]}

Du, Zhengyin ^{[1
]}

机构：

[1] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2022年 / 20卷 / 34期

基金：

中国国家自然科学基金;

关键词：

VISIBLE-LIGHT PHOTOCATALYSIS; METAL-FREE; ELECTRON-TRANSFER; PHOTOREDOX CATALYSIS; SELECTIVE OXIDATION; EOSIN; STATE; ORGANOCATALYSIS; HETEROCYCLES; ABSORPTION;

D O I：

10.1039/d2ob00807f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the past decade, visible light photoredox catalysis has been established as a gentle and powerful strategy for the activation of organic molecules. As an important part of this, organic photocatalysts are widely used in chemical synthesis due to their attributes, such as cheapness and relatively high redox potential. In this article, we review the related organic reactions promoted by visible light in the presence of various organic photocatalysts over the past 5 years. The reaction mechanisms involving single electron transfer, energy transfer and proton-coupled electron transfer are also discussed. The recovery and reuse of some supported organic photocatalysts are highlighted. Moreover, prospects for the development of organic photocatalysts are emphasized.

引用

页码：6721 / 6740

页数：20

共 97 条

[1] Radical Fluoroalkylation Reactions [J].

Barata-Vallejo, Sebastian ;

Victoria Cooke, Maria ;

Postigo, Al .

ACS CATALYSIS, 2018, 8 (08) :7287-7307

[2] Heterogeneous mesoporous manganese/cobalt oxide catalysts for selective oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran [J].

Biswas, Sourav ;

Dutta, Biswanath ;

Mannodi-Kanakkithodi, Arun ;

Clarke, Ryan ;

Song, Wenqiao ;

Ramprasad, Ramamurthy ;

Suib, Steven L. .

CHEMICAL COMMUNICATIONS, 2017, 53 (86) :11751-11754

[3] Bond dissociation energies of organic molecules [J].

Blanksby, SJ ;

Ellison, GB .

ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (04) :255-263

[4] Recent advancements in the development of molecular organic photocatalysts [J].

Bobo, M. Victoria ;

Kuchta, Joseph J. ;

Vannucci, Aaron K. .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 19 (22) :4816-4834

[5]

Bockman TM, 1997, J PHYS ORG CHEM, V10, P542

[6]

Brasholz, 2019, GEORG THIEME VERLAG

[7] Acyl Radicals from Acylsilanes: Photoredox-Catalyzed Synthesis of Unsymmetrical Ketones [J].

Capaldo, Luca ;

Riccardi, Riccardo ;

RaveIli, Davide ;

Fagnoni, Maurizio .

ACS CATALYSIS, 2018, 8 (01) :304-309

[8]

Cecotka M.C., 2020, NAT CATAL, V3, P872

[9] Phenyl Benzo[b]phenothiazine as a Visible Light Photoredox Catalyst for Metal-Free Atom Transfer Radical Polymerization [J].

Dadashi-Silab, Sajjad ;

Pan, Xiangcheng ;

Matyjaszewski, Krzysztof .

CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (25) :5972-5977

[10] A highly reducing metal-free photoredox catalyst: design and application in radical dehalogenations [J].

Discekici, Emre H. ;

Treat, Nicolas J. ;

Poelma, Saemi O. ;

Mattson, Kaila M. ;

Hudson, Zachary M. ;

Luo, Yingdong ;

Hawker, Craig J. ;

de Alaniz, Javier Read .

CHEMICAL COMMUNICATIONS, 2015, 51 (58) :11705-11708

← 1 2 3 4 5 6 7 8 9 10 →