Steric Effects Control Self-Sorting in Self-Assembled Clusters

被引：109

作者：

Johnson, Amber M. ^{[1
]}

Hooley, Richard J. ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 11期

关键词：

RECOGNITION; DISCRETE; LIGANDS; SYSTEMS;

D O I：

10.1021/ic2001688

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Endohedrally functionalized bis(pyridine) ligands show the ability to self-discriminate when treated with coordinating metals to form self-assembled clusters. Self-sorting between components is controlled by substitution on the interior of the complex. Tuning the size of the internal substituent allows selective heterocluster formation, determined by noncovalent and space-filling interactions. This novel method of self-sorting allows discrimination between ligands of identical geometry and donor type.

引用

页码：4671 / 4673

页数：3

共 29 条

[1] Disproportionation and self-sorting in molecular encapsulation
Ajami, Dariush
Hou, Jun-Li
Dale, Trevor J.
Barrett, Elizabeth
Rebek, Julius, Jr.
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (26) : 10430 - 10434
[2] MULTICOMPONENT SELF-ASSEMBLY - SPONTANEOUS FORMATION OF A CYLINDRICAL COMPLEX FROM 5 LIGANDS AND 6 METAL-IONS
BAXTER, P
LEHN, JM
DECIAN, A
FISCHER, J
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (01): : 69 - 72
[3] Self-assembly of a novel macrotricyclic Pd(II) metallocage encapsulating a nitrate ion
Chand, DK
Biradha, K
Fujita, M
[J]. CHEMICAL COMMUNICATIONS, 2001, (17) : 1652 - 1653
[4] THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL
DEWAR, MJS
ZOEBISCH, EG
HEALY, EF
STEWART, JJP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) : 3902 - 3909
[5] Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels
Fiedler, D
Leung, DH
Bergman, RG
Raymond, KN
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) : 349 - 358
[6] Molecular paneling via coordination
Fujita, M
Umemoto, K
Yoshizawa, M
Fujita, N
Kusukawa, T
Biradha, K
[J]. CHEMICAL COMMUNICATIONS, 2001, (06) : 509 - 518
[7] Self-sorting molecular clips
Ghosh, Soumyadip
Wu, Anxin
Fettinger, James C.
Zavalij, Peter Y.
Isaacs, Lyle
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (15) : 5915 - 5925
[8] Monitoring Self-Sorting by Electrospray Ionization Mass Spectrometry: Formation Intermediates and Error-Correction during the Self-Assembly of Multiply Threaded Pseudorotaxanes
Jiang, Wei
Schafer, Andreas
Mohr, Parveen Choudhary
Schalley, Christoph A.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (07) : 2309 - 2320
[9] Folding of coordination polymers into double-stranded helical organization
Kim, Ho-Joong
Lee, Eunji
Kim, Min Gyu
Kim, Min-Cheol
Lee, Myongsoo
Sim, Eunji
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (13) : 3883 - 3888
[10] SELF-RECOGNITION IN HELICATE SELF-ASSEMBLY - SPONTANEOUS FORMATION OF HELICAL METAL-COMPLEXES FROM MIXTURES OF LIGANDS AND METAL-IONS
KRAMER, R
LEHN, JM
MARQUISRIGAULT, A
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1993, 90 (12) : 5394 - 5398

← 1 2 3 →