Design and synthesis of bichromophores for nonlinear optical applications in polymer films

被引：7

作者：

Gao, Junkuo ^{[1
]}

Cui, Yuanjing ^{[1
]}

Yu, Jiancan ^{[1
]}

Lin, Wenxin ^{[1
]}

Wang, Zhiyu ^{[1
]}

Qian, Guodong ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2011年 / 71卷 / 04期

基金：

中国国家自然科学基金;

关键词：

Bichromophore; Nonlinear optics; Tether groups; Second harmonic generation; Polymer film; ORGANIC ELECTROOPTIC MATERIALS; ALKOXYSILANE DYE; CHROMOPHORES; TRICHROMOPHORE; ATTACHMENT; DENDRIMERS;

D O I：

10.1016/j.reactfunctpolym.2011.01.009

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Three bichromophores were designed and synthesized by linking a vinylthiophene-conjugated chromophore with different tether groups via esterification. Second harmonic generation measurements of nonlinear polymer films revealed that the second harmonic generation coefficients of the films containing the bichromophore and using 3-phenoxypropane-1,2-diyl succinic diester as the tether group were improved in comparison with the mono-chromophore-doped polymer films. However, the second harmonic generation coefficients of the polymer films containing bichromophores using isophthalic ester as the tether group were decreased. Overall, the results indicate that the 3-phenoxypropanc-1.2-diyl succinic diester tether group has potential applications in the design and synthesis of multi-chromophoric dendrimers with large macroscopic optical nonlinearity. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：496 / 501

页数：6

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