The Electrochemical Behavior of Silicon on the Titanium Electrodes in [Bmim] OTf-SiCl4-PC System

被引：0

作者：

Zhang, Yuehong ^{[1
]}

Li, Yaqiong ^{[2
]}

Li, Binchuan ^{[1
]}

Tao, Shaohu ^{[1
]}

机构：

[1] Northeastern Univ Qinhuangdao, Qinhuangdao 066004, Hebei, Peoples R China

[2] Dalian Univ Technol, Dalian 116024, Liaoning, Peoples R China

来源：

2015 2ND INTERNATIONAL CONFERENCE ON INTELLIGENT MATERIALS AND MECHATRONICS (IMM 2015) | 2015年

关键词：

Silicon; Ionic liquids; Electrodeposition; Electrochemistry; TEMPERATURE IONIC LIQUID; ROOM-TEMPERATURE; MOLTEN-SALT; CHLORIDE; ALUMINUM; GOLD; TI;

D O I：

暂无

中图分类号：

TP [自动化技术、计算机技术];

学科分类号：

0812 ;

摘要：

Study on the Cathodic process of titanium electrode in the [Bmim] OTf-SiCl4-PC system by electrochemically. Analysis on the mechanism of silicon deposition, and electrodeposition experiments. The results showed that: Cathodic reaction is an irreversible reaction, Silicon ions in the titanium electrode nucleation process is instantaneous nucleation hemispherical diffusion growth process, DC current density: 2.7mA.cm(-2), Temperature: 40 degrees C, obtain a dense deposits.

引用

页码：101 / 104

页数：4

共 9 条

[1] Electrochemical studies of gold and chloride in ionic liquids
Aldous, Leigh
Silvester, Debbie S.
Villagran, Constanza
Pitner, William R.
Compton, Richard G.
Lagunas, M. Cristina
Hardacre, Christopher
[J]. NEW JOURNAL OF CHEMISTRY, 2006, 30 (11) : 1576 - 1583
[2] Electrodeposition of nanoscale silicon in a room temperature ionic liquid
El Abedin, SZ
Borissenko, N
Endres, F
[J]. ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (05) : 510 - 514
[3] Electrodeposition of a thin germanium film on gold from a room temperature ionic liquid
Endres, F
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (15) : 3165 - 3174
[4] In situ STM studies on germanium tetraiodide electroreduction on Au(111) in the room temperature molten salt 1-butyl-3-methylimidazolium hexafluorophosphate
Endres, F
Schrodt, C
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2000, 2 (24) : 5517 - 5520
[5] Electrodeposition of aluminium from ionic liquids:: Part I -: electrodeposition and surface morphology of aluminium from aluminium chloride (AlCl3)-l-ethyl-3-methylimidazolium chloride ([EMIm]Cl) ionic liquids
Jiang, T.
Brym, M. J. Chollier
Dube, G.
Lasia, A.
Brisard, G. M.
[J]. SURFACE & COATINGS TECHNOLOGY, 2006, 201 (1-2) : 1 - 9
[6] Preparation of a novel fluorosilicate salt for electrodeposition of silicon at low temperature
Katayama, Y
Yokomizo, M
Miura, T
Kishi, T
[J]. ELECTROCHEMISTRY, 2001, 69 (11) : 834 - 836
[7] Electrochemical behavior of silver in 1-ethyl-3-methylimidazolium tetrafluoroborate molten salt
Katayama, Y
Dan, S
Miura, T
Kishi, T
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (02) : C102 - C105
[8] Electrodeposition of Ti from TiCl4 in the ionic liquid 1-methyl-3-butyl-imidazolium bis (trifluoro methyl sulfone) imide at room temperature:: study on phase formation by in situ electrochemical scanning tunneling microscopy
Mukhopadhyay, I
Aravinda, CL
Borissov, D
Freyland, W
[J]. ELECTROCHIMICA ACTA, 2005, 50 (06) : 1275 - 1281
[9] Electrochemistry of titanium and the electrodeposition of Al-Ti alloys in the Lewis acidic aluminum chloride-1-ethyl-3-methylimidazolium chloride melt
Tsuda, T
Hussey, CL
Stafford, GR
Bonevich, JE
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (04) : C234 - C243

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