Palladium-gold oxo complexes

被引:18
作者
Singh, A [1 ]
Sharp, PR [1 ]
机构
[1] Univ Missouri, Columbia, MO 65211 USA
关键词
D O I
10.1039/b504808g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Treatment of L2PdCl2 (L-2 = 4,4'-di-tert-butyl- 2,2'-bipyridine) with [( L' Au)(3)(mu(3)-O)] BF4 ( L' = PPh3) has yielded cationic oxo complexes with core formulas Pd2Au2O2 and Pd4AuO3 thereby doubling the number of structurally characterized Pd oxo complexes.
引用
收藏
页码:2080 / 2081
页数:2
相关论文
共 34 条
[1]   Mixed metal bis(μ-oxo) complexes with [CuM(μ-O)2]n+ (M = Ni(III) or Pd(II)) cores [J].
Aboelella, NW ;
York, JT ;
Reynolds, AM ;
Fujita, K ;
Kinsinger, CR ;
Cramer, CJ ;
Riordan, CG ;
Tolman, WB .
CHEMICAL COMMUNICATIONS, 2004, (15) :1716-1717
[2]   Platinum and palladium imido and oxo complexes with small natural bite angle diphosphine ligands [J].
Anandhi, U ;
Holbert, T ;
Lueng, D ;
Sharp, PR .
INORGANIC CHEMISTRY, 2003, 42 (04) :1282-1295
[3]   RETRACTED: A late-transition metal oxo complex: K7Na9[O=PtIV(H2O)L2]. L = [PW9O34]9- (Retracted Article) [J].
Anderson, TM ;
Neiwert, WA ;
Kirk, ML ;
Piccoli, PMB ;
Schultz, AJ ;
Koetzle, TF ;
Musaev, DG ;
Morokuma, K ;
Cao, R ;
Hill, CL .
SCIENCE, 2004, 306 (5704) :2074-2077
[4]  
Blackman AG, 2000, STRUCT BOND, V97, P179
[5]  
Chusuei CC, 2001, TOP CATAL, V14, P71
[6]   Gold(I) and gold(III) complexes with anionic oxygen donor ligands: hydroxo, oxo and alkoxo complexes [J].
Cinellu, MA ;
Minghetti, G .
GOLD BULLETIN, 2002, 35 (01) :11-20
[7]   Experimental and theoretical studies of the d8-d10 interaction between Pd(II) and Au(I):: Bis(chloro[(phenylthiomethyl)diphenylphosphine]gold(I))-dichloropalladium(II) and related systems [J].
Crespo, O ;
Laguna, A ;
Fernández, EJ ;
López-de-Luzuriaga, JM ;
Jones, PG ;
Teichert, M ;
Monge, M ;
Pyykkö, P ;
Runeberg, N ;
Schütz, M ;
Werner, HJ .
INORGANIC CHEMISTRY, 2000, 39 (21) :4786-4792
[8]   [Me2NN]Co(η6-toluene):: O=O, N= N, and O=N bond cleavage provides, β-diketiminato cobalt μ-oxo and imido complexes [J].
Dai, XL ;
Kapoor, P ;
Warren, TH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (15) :4798-4799
[9]   A monomeric nickel-dioxygen adduct derived from a nickel(I) complex, and O2 [J].
Fujita, K ;
Schenker, R ;
Gu, WW ;
Brunold, TC ;
Cramer, SP ;
Riordan, CG .
INORGANIC CHEMISTRY, 2004, 43 (11) :3324-3326
[10]   Copper, silver and gold in catalysis - Preface [J].
Haruta, M ;
Souma, Y .
CATALYSIS TODAY, 1997, 36 (01) :1-1