Four novel 3D copper(II) coordination polymers with different topologies

被引：154
|
作者：
Yang, J [1 ]
Ma, JF [1 ]
Liu, YY [1 ]
Li, SL [1 ]
Zheng, GL [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 11期
关键词：
coordination polymers; copper; self-assembly; supramolecular chemistry; topology;
D O I：
10.1002/ejic.200400960
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of Cu-II coordination polymers with different topologies, namely [CuL(L-1)]center dot 2H(2)O (1), [CuL1.5(L-2)]center dot 3H(2)O (2), [CuL(L-3)]center dot 3H(2)O (3) and [Cu2L2.5(L-4)(H2O)]center dot 10H(2)O (4) [L = 1,1 '-(1,4-butanediyl)bis(imidazole), H2L1 fumaric acid, H2L2 = 1,1 '-ferrocenedicarboxylic acid, H2L3 = succinic acid, and H4L4 = pyromellitic acid], are presented. Different polymeric frameworks are obtained by varying the polycarboxylate anions. These include the threefold interpenetrated diamond structure of 1, the rare twofold interpenetrated 4 6 6 network of 2, and two planar four-connected networks of 3 and 4, which display an unusual Archimedean-type (6(5)8) (6(4)8(2)) net containing two different types of nodes and a (56(4)8) (5(2)6(2)8(2))(2)(68(4)10)(5(4)6(2)) net containing four different types of nodes, respectively. Thermogravimetric analysis (TGA) curves of 1, 2, 3, and 4 exhibit three similar weight-loss stages. (c) Wiley-VCH Verlag GmbH & Co.
引用
收藏
页码：2174 / 2180
页数：7
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