Four novel 3D copper(II) coordination polymers with different topologies

被引：154

作者：

Yang, J ^{[1
]}

Ma, JF ^{[1
]}

Liu, YY ^{[1
]}

Li, SL ^{[1
]}

Zheng, GL ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 11期

关键词：

coordination polymers; copper; self-assembly; supramolecular chemistry; topology;

D O I：

10.1002/ejic.200400960

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of Cu-II coordination polymers with different topologies, namely [CuL(L-1)]center dot 2H(2)O (1), [CuL1.5(L-2)]center dot 3H(2)O (2), [CuL(L-3)]center dot 3H(2)O (3) and [Cu2L2.5(L-4)(H2O)]center dot 10H(2)O (4) [L = 1,1 '-(1,4-butanediyl)bis(imidazole), H2L1 fumaric acid, H2L2 = 1,1 '-ferrocenedicarboxylic acid, H2L3 = succinic acid, and H4L4 = pyromellitic acid], are presented. Different polymeric frameworks are obtained by varying the polycarboxylate anions. These include the threefold interpenetrated diamond structure of 1, the rare twofold interpenetrated 4 6 6 network of 2, and two planar four-connected networks of 3 and 4, which display an unusual Archimedean-type (6(5)8) (6(4)8(2)) net containing two different types of nodes and a (56(4)8) (5(2)6(2)8(2))(2)(68(4)10)(5(4)6(2)) net containing four different types of nodes, respectively. Thermogravimetric analysis (TGA) curves of 1, 2, 3, and 4 exhibit three similar weight-loss stages. (c) Wiley-VCH Verlag GmbH & Co.

引用

页码：2174 / 2180

页数：7

共 50 条

[1] Syntheses, crystal structures and properties of a series of 3D cadmium coordination polymers with different topologies
He, Xiang
Zhang, Jian
Wu, Xiao-Yuan
Lu, Can-Zhong
INORGANICA CHIMICA ACTA, 2010, 363 (08) : 1727 - 1734
[2] Two 3D Copper(II/I) Coordination Polymers: Structures, Energetic and Magnetic Properties
Gao, Wei
Huang, Hong
Liu, Feng
Zhang, Xiumei
Liu, Jieping
CHEMISTRYSELECT, 2020, 5 (07): : 2185 - 2189
[3] Synthesis, structures and magnetic properties of four 3D heterometallic cobalt(II)-barium(II) coordination polymers
Sun, Qiao-Zhen
Lu, Jiang-Feng
Chai, Li-Yuan
Liu, Na-Wei
Zhu, Xiao-Wei
Kang, Hui-Yuan
Liu, Hui
TRANSITION METAL CHEMISTRY, 2018, 43 (05) : 439 - 450
[4] Synthesis, structures and magnetic properties of four 3D heterometallic cobalt(II)–barium(II) coordination polymers
Qiao-Zhen Sun
Jiang-Feng Lu
Li-Yuan Chai
Na-Wei Liu
Xiao-Wei Zhu
Hui-Yuan Kang
Hui Liu
Transition Metal Chemistry, 2018, 43 : 439 - 450
[5] 3D copper coordination polymers based on N-heterocyclic ligands with different topology
He, Xiang
Wang, Zhao-Xi
Xing, Fei-Fei
Li, Ming-Xing
INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (03) : 417 - 420
[6] Heterometallic Copper(II) Potassium 3D Coordination Polymers Driven by Multifunctionalized Azo Derivatives of β-Diketones
Kopylovich, Maximilian N.
Karabach, Yauhen Yu.
Mahmudov, Kamran T.
Haukka, Matti
Kirillov, Alexander M.
Figiel, Pawel J.
Pombeiro, Armando J. L.
CRYSTAL GROWTH & DESIGN, 2011, 11 (10) : 4247 - 4252
[7] Coordination polymers composed of copper(II), trimesic acid, and imidazole: 3D architecture stabilized by hydrogen bonding
Cheng, DP
Khan, MA
Houser, RP
INORGANIC CHEMISTRY, 2001, 40 (27) : 6858 - +
[8] Four novel lanthanide(III) coordination polymers with 3D network structures containing 2-fold interpenetration
Chu, Wen-Juan
Hou, Xiao-Wei
Zhao, Qing-Huan
Fan, Yao-Ting
Hou, Hong-Wei
INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (01) : 22 - 25
[9] A porous supramolecular architecture from a copper(II) coordination polymer with a 3D four-connected 86 net
Ma, JF
Yang, J
Zheng, GL
Li, L
Liu, JF
INORGANIC CHEMISTRY, 2003, 42 (23) : 7531 - 7534
[10] Two Coordination Polymers with Rare Topologies Based on Copper(II) and Ligands Generated by In Situ Reactions
Li, Baiyan
Jin, Di
Ma, Benhua
Liu, Dan
Li, Guanghua
Shi, Zhan
Feng, Shouhua
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (01) : 35 - 38

← 1 2 3 4 5 →